919087-35-7

Basic information

• Product Name: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne
• Synonyms: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne
• CAS NO: 919087-35-7
• Molecular Weight: 210.663
• Mol File: 919087-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne(919087-35-7)
• EPA Substance Registry System: (E)-1-chloro-8-phenyl-1-octene-3,5,7-triyne(919087-35-7)

Safety Data

• Hazardous Substances Data: 919087-35-7(Hazardous Substances Data)

Upstream product

• 919087-27-7 (E)-1-chloro-6-phenyl-1-hexene-3,5-diyne 
• 28540-81-0 (E) 2-iodo-1-chloroethylene 
• 536-74-3 phenylacetylene 
• 18685-03-5 (E)-1-(4-chlorobut-3-en-1-ynyl)benzene 

Downstream Products

• 596122-61-1 1-(trimethylsilyl)-8-phenyl-1,3,5,7-octatetrayne 

Relevant articles and documents

Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling

(Diagram presented) Iteration of a Pd-catalyzed reaction of alkynyl- and oligoynylzincs with (E)-ICH=CHCl followed by metalation-termination with electrophiles(E) has provided a linear route to conjugated tri- and tetraynes, and Pd-catalyzed monoalkynylation of 1,1-dibromoenynes accompanied by dehydrobromination has provided a convergent route to conjugated tri-, tetra-, and pentaynes. Both display unprecedented high efficiency and selectivity.