921200-50-2Relevant articles and documents
Rhodium-catalyzed hydrosilylation of internal alkynes with silane reagents bearing heteroatom substituent. Studies on the regio-/stereochemistry and transformation of the produced alkenylsilanes by rhodium-catalyzed conjugate addition
Sanada, Tomoyuki,Kato, Tsuyoshi,Mitani, Makoto,Mori, Atsunori
, p. 51 - 54 (2007/10/03)
Rhodium-catalyzed hydrosilylation of internal alkynes furnished (E)-1,2-disubstituted alkenylsilanes. The obtained alkenylsilane was subjected to reaction with α,β-unsaturated carbonyl compounds in the presence of a rhodium catalyst to undergo conjugate a