94480-29-2

Basic information

• Product Name: (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one
• Synonyms: (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one
• CAS NO: 94480-29-2
• Molecular Weight: 218.252
• Mol File: 94480-29-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one(94480-29-2)
• EPA Substance Registry System: (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one(94480-29-2)

Safety Data

• Hazardous Substances Data: 94480-29-2(Hazardous Substances Data)

Upstream product

• 94480-28-1 (S)-5-Benzyloxy-1-[1,3]dioxolan-2-yl-4-hydroxy-pentan-2-one 
• 54125-02-9 danishefsky's diene 
• 60656-87-3 benzyloxyacetoaldehyde 
• 194233-66-4 (1E)-3-{[tert-butyl(dimethyl)silyl]oxy}-N,N-dimethyl-1,3-butadien-1-amine 
• 602326-63-6 (S)-2-(benzyloxymethyl)-3,6-dihydro-2H-pyran 
• 100-39-0 benzyl bromide 
• 172323-66-9 (S)-(-)-(3,6-Dihydro-2H-pyran-2-yl)methanol 
• 80127-39-5 2-benzyloxymethyl-2,3-dihydropyran-4-one 
• 94371-08-1 (5S)-5-(Hydroxymethyl)-3-<(1,3-dioxolan-2-yl)methyl)>-4,5-dihydroisoxazole 
• 90344-31-3 (5S)-5-<(4R)-(2,2-dimethyl-1,3-dioxolan-4-yl)>-3-<(1,3-dioxolan-2-yl)methyl>-4,5-dihydroisoxazole 
• 82891-99-4 ethylene ketal of 3-nitropropanal 
• 94480-27-0 (5S)-5-<(phenylmethoxy)methyl>-3-<(1,3-dioxolan-2-yl)methyl>-4,5-dihydroisoxazole 
• 94371-07-0 (5S)-5-<(1R)-1,2-dihydroxyethyl>-3-<(1,3-dioxolan-2-yl)methyl>-4,5-dihydroisoxazole 

Downstream Products

• 443339-54-6 (2S,4S)-2-benzyloxymethyl-3,4-dihydro-2H-pyran-4-ol 
• 94371-04-7 methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside 
• 94371-09-2 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside 
• 86030-94-6 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-β-D-erythro-hexopyranoside 
• 86030-95-7 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-α-D-erythro-hexopyranoside 
• 189623-47-0 (2S,6R)-2-Benzyloxymethyl-6-(2-methoxymethoxy-ethyl)-3,6-dihydro-2H-pyran 
• 190005-97-1 Acetic acid (2S,4S)-2-benzyloxymethyl-3,4-dihydro-2H-pyran-4-yl ester 
• 189623-46-9 2-((2R,6S)-6-Benzyloxymethyl-5,6-dihydro-2H-pyran-2-yl)-ethanol 
• 94480-26-9 (2S,6S)-tetrahydro-2-methoxy-6-<(phenylmethoxy)methyl>-4H-pyran-4-one 
• 94480-30-5 (2S,6R)-2-Benzyloxymethyl-4,4,6-trimethoxy-tetrahydro-pyran 
• 80127-49-7 (2S,6S)-2-Benzyloxymethyl-4,4,6-trimethoxy-tetrahydro-pyran 

Relevant articles and documents

Catalytic enantioselective synthesis of dihydropyrones via formal hetero Diels-Alder reactions of 'Danishefsky's diene' with aldehydes

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Methods of performing cycloadditions, reaction mixtures, and methods of performing asymmetric catalytic reactions

Methods of performing cycloadditions are described that include (a) combining a first reactant and a second reactant in a hydrogen bonding solvent to form a reaction mixture; and (b) reacting the first reactant and the second reactant to form a cycloadduc

A new dirhodium(II) carboxamidate complex as a chiral Lewis acid catalyst for enantioselective hetero-Diels-Alder reactions

Excellent enantioselectivities (up to 99% ee) and turnover numbers (up to 48000) were attained in the hetero-Diels-Alder reaction of a diverse range of aldehydes and activated dienes catalyzed by [Rh2(S-bptpi) 4] (see scheme).