944836-37-7Relevant articles and documents
Branch-selective allylic C-H carboxylation of terminal alkenes by pd/sox catalyst
Kondo, Hiroki,Yu, Feng,Yamaguchi, Junichiro,Liu, Guosheng,Itami, Kenichiro
, p. 4212 - 4215 (2014/11/07)
A ligand-controlled branch-selective allylic C-H carboxylation through Pd catalysis is described. The developed catalytic system, which consists of Pd(OAc)2, sulfoxide-oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.
A facile and modular synthesis of phosphinooxazoline ligands
Tani, Kousuke,Behenna, Douglas C.,McFadden, Ryan M.,Stoltz, Brian M.
, p. 2529 - 2531 (2008/02/05)
The copper(I) iodide catalyzed phosphine/aryl halide coupling procedure of Buchwald et al. provides modular, robust, and scaleable access to phosphinooxazoline (PHOX) ligands. The advantages of this method are highlighted by the convenient synthesis of PH