947258-69-7

Basic information

• Product Name: (E)-3-phenylprop-2-enyl N-tosyloxycarbamate
• Synonyms: (E)-3-phenylprop-2-enyl N-tosyloxycarbamate
• CAS NO: 947258-69-7
• Molecular Weight: 347.392
• Mol File: 947258-69-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-3-phenylprop-2-enyl N-tosyloxycarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-phenylprop-2-enyl N-tosyloxycarbamate(947258-69-7)
• EPA Substance Registry System: (E)-3-phenylprop-2-enyl N-tosyloxycarbamate(947258-69-7)

Safety Data

• Hazardous Substances Data: 947258-69-7(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 103723-92-8 (E)-3-phenylprop-2-enyl N-hydroxycarbamate 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1078-70-2 3-phenylprop-2-enyloxycarbonylamine 

Relevant articles and documents

Copper-catalyzed tethered aziridination of unsaturated N-tosyloxy carbamates

(Chemical Equation Presented) Aziridines were formed by copper-catalyzed intramolecular nitrene addition to alkenes. The carbamate group was used as the tether between the alkene and the nitrene. Subsequent nucleophilic attack of the aziridine was accomplished using RSH, R2NH, N3 -, or ROH as the nucleophile. This addition was found to be regio- and stereoselective. This methodology has been used to demonstrate its utility in the regio-and stereoselective synthesis of a 1,2-diamino-3- hydroxycyclohexane. This substitution pattern is found in natural products such as Tamiflu.