95111-00-5

Basic information

• Product Name: Benzene, 1-(2,2-dibromo-1-methylethenyl)-4-methoxy-
• CAS NO: 95111-00-5
• Molecular Formula: C10H10Br2O
• Molecular Weight: 305.997
• Mol File: 95111-00-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2,2-dibromo-1-methylethenyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2,2-dibromo-1-methylethenyl)-4-methoxy-(95111-00-5)
• EPA Substance Registry System: Benzene, 1-(2,2-dibromo-1-methylethenyl)-4-methoxy-(95111-00-5)

Safety Data

• Hazardous Substances Data: 95111-00-5(Hazardous Substances Data)

Upstream product

• 558-13-4 carbon tetrabromide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 6310-14-1 4'-methoxyacetophenone hydrazone 

Downstream Products

• 95110-88-6 C₂₀H₂₀O₂ 
• 2749-94-2 1-methoxy-4-(prop-1-yn-1-yl)benzene 
• 872782-53-1 2-(4-methoxyphenyl)-N-phenylpropanamide 

Relevant articles and documents

Photocatalytic Isomerization of Styrenyl Halides: Stereodivergent Synthesis of Functionalized Alkenes

An efficient and general method for the isomerization of styrenyl halides under different photocatalytic conditions (fac-Ir(ppy)3 in methanol for E to Z isomerization and fluorescein in 1,4-dioxane for Z to E isomerization, respectively) is disclosed. A series of stereospecific transformations constitute preliminary validation of this strategy in the synthesis of functionalized alkenes, including two diaryl alkenes, a styrenyl boronic ester and an enyne. The photocatalytic isomerization and subsequent cross coupling reaction can be run in a one-pot manner. The stereodivergent synthesis of all four isomers of a conjugated diene, as well as the antitumor agent DMU-212 and its (Z)-isomer highlights the synthetic applicability of this method.

Horner-Wadsworth-Emmons modification for Ramirez gem-dibromoolefination of aldehydes and ketones using P(Oi-Pr)3

A simple procedure for the use of triisopropylphosphite in the Ramirez olefination is described. This reagent is equally or more reactive than PPh 3 toward aldehydes and ketones in the gem-dibromoolefination of aldehydes and ketones. Under the

A NEW AND CONVENIENT SYNTHESIS OF ARYL-SUBSTITUTED BUTATRIENES USING NICKEL-CATALYZED COUPLING OF ARYL-SUBSTITUTED 1,1-DIBROMOETHENES

The reactions of aryl-substituted 1,1-dibromoethenes with in situ generated tetrakis(triphenylphosphine)nickel(0) in the presence of tetraethylammonium iodide give aryl-substituted butatrienes.