95606-95-4Relevant articles and documents
A NEW METHOD FOR NUCLEOPHILIC OXYMETHYLATION USING α-ALKOXYSILANES. SYNTHESIS OF UNSYMMETRICAL 1,2-DIOLS
Tsuge, Otohiko,Kanemasa, Shuji,Nagahama, Hideki,Tanaka, Junji
, p. 1803 - 1806 (2007/10/02)
Desilylation of α-alkoxysilanes offers the convenient generation of carbinyl carbanions which react with a variety of carbonyl compounds giving mono-protected 1,2-diols of unsymmetrical type.Dehydration of these unsymmetrical diols leads to the regioselective formation of methyl ketones.