95883-10-6Relevant articles and documents
Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf
Hashimoto, Takuya,Kutubi, Md. Shahajahan,Izumi, Takayuki,Rahman, Ataur,Kitamura, Tsugio
experimental part, p. 99 - 105 (2011/02/16)
Hydroarylation of propiolic acids with various arenes in TFA proceeded efficiently in the presence of FeCl3/AgOTf catalyst system. In the case of electron-rich arenes, the iron-catalyzed hydroarylation gave cinnamic acids in moderate to high yields. The hydroarylation of phenylacetylene was observed but the catalyst was not effective under the same conditions.
Oxidative Coupling of 1-(2,6-Dichlorobenzoyl)pyrroles and -pyrazoles and Alkyl Acrylates by Palladium(II) Acetate
Itahara, Toshio,Kawasaki, Kazukuni,Ouseto, Fumio
, p. 3488 - 3493 (2007/10/02)
Treatments of 1-(2,6-dichlorobenzoyl)-, 3-acetyl-1-(2,6-dichlorobenzoyl)-, 1-(2,6-dichlorobenzoyl)-2-formyl-, and 1-(phenylsulfonyl)pyrroles with palladium acetate and alkyl acrylates gave the corresponding α-alkenyl-substituted pyrroles in good yields, while the reaction of 1-(2,6-dichlorobenzoyl)-2,5-dimethylpyrrole gave small amounts of β-alkenyl-substituted pyrroles.Under similar conditions, 1-(2,6-dichlorobenzoyl)pyrazole and 1-(2,6-dichlorobenzoyl)-3,5-dimethylpyrazole reacted with palladium acetate and alkyl acrylates to give the corresponding 4-alkenyl-substituted pyrazoles.The reaction of 1-(2,6-dichlorobenzoyl)-4-methylpyrazole gave 5-alkenyl-substituted pyrazole.
