96154-40-4Relevant articles and documents
Boron trifluoride-mediated alkylation of diphenylphosphine with tert-alkyl fluoride
Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4873 - 4875 (2007/10/03)
(Chemical Equation Presented) Treatment of tertiary alkyl fluoride with diphenylphosphine in the presence of a stoichiometric amount of boron trifluoride etherate yields the corresponding tert-alkyldiphenylphosphine despite the coexistence of the strong L
Products Active on Mosquitoes: Part III - Synthesis of Biologically Active 3,7-Dimethyl-6-octene-1,8-diol Diethers
Phadnis, A. P.,Nanda, B.,Patwardhan, Sarita A.,Powar, P.,Sharma, R. N.
, p. 867 - 870 (2007/10/02)
Mixed diethers (IIIa-s) have been prepared from 8-hydroxy-monoethers (IIa-g) which in turn have been obtained from citronellyl ethers (Ia-g) by selenium oxidation.Most of the diethers are oviposition deterrent, while some of them also show inhibition towards the development of mosquitoes.
Synthesis of the Proposed Penultimate Biosynthetic Triene Intermediate of Monensin A
Patel, Dinesh V.,VanMiddlesworth, Frank,Donaubauer, John,Gannett, Peter,Sih, Charles J.
, p. 4603 - 4614 (2007/10/02)
A convergent chiral synthesis of the putative biosynthetic triene precursor, 2b, has been accomplished.Our strategy entails the successive assembly of three key chiral synthons, prepared by enzymatic and microbial techniques.