97627-64-0Relevant articles and documents
Formation of Oxetanes via Photo-sensitized Oxidation of Enamines
Schumann, Dieter,Geirsson, Jon,Naumann, Anneliese
, p. 1927 - 1935 (2007/10/02)
Photooxidation of enamines 1 and 5 in toluene give rise to the formation of the usual reaction products.In methanol, however, the oxetanes 8 and 13, respectively, are isolated as the main photooxidation products.Both the mechanism of their formation as well as some reactions of 8 and 13 are discussed.Oxidation of 13 with m-chloroperbenzoic acid produces the aldehyde 15 via a multi-step reaction.