- No-carrier-added radioiodination of triolborates, water-soluble complexes of boronic acids
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A convenient and rapid synthesis of iodine-123 labeled aryl and heteroaryl iodides from water-soluble complexes of aryl- and heteroarylboronic acids has been developed. Copyright
- Akula, Murthy R.,Yao, Min-Liang,Kabalka, George W.
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- Silyl-protected dioxaborinanes: Application in the Suzuki cross-coupling reaction
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The synthesis of a range of novel silyl-protected dioxaborinanes as a column- and bench-stable boron reagent were found to be advantageous to achieving good yields in palladium-catalysed cross-coupling reactions under standard conditions. This journal is The Royal Society of Chemistry.
- Goggins, Sean,Rosevere, Eleanor,Bellini, Clement,Allen, Joseph C.,Marsh, Barrie J.,Mahon, Mary F.,Frost, Christopher G.
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supporting information
p. 47 - 52
(2014/01/06)
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- Rhodium-catalysed enantioselective synthesis of 4-arylchroman-2-ones
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The rhodium-catalysed enantioselective 1,4-addition of organoboron reagents to arylidene Meldrum's acids as acceptors, allows convenient access to 4-arylchroman-2-ones with good to excellent levels of enantioselectivity. The use of silyl-protected dioxabo
- Allen, Joseph C.,Kociok-Koehn, Gabriele,Frost, Christopher G.
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supporting information; experimental part
p. 32 - 35
(2012/01/06)
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- Triolborates: water-soluble complexes of arylboronic acids as precursors to iodoarenes
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A facile synthesis of aryl and heteroaryl iodides from water-soluble complexes of aryl- and heteroarylboronic acids has been developed.
- Akula, Murthy R.,Yao, Min-Liang,Kabalka, George W.
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experimental part
p. 1170 - 1171
(2010/04/23)
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- Cyclic triolborates: Air- and water-stable ate complexes of organoboronic acids
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(Chemical Equation Presented) A borate in the hand is a convenient reagent for palladium- and copper-catalyzed C-C and C-N bond-forming reactions, especially when, like the title bench-stable complexes, it demonstrates high transmetalation efficiency. Cyclic triolborates can be synthesized readily from organoboronic acids (see scheme), can be handled and stored without special precautions, and are relatively soluble in organic solvents.
- Yamamoto, Yasunori,Takizawa, Miho,Yu, Xiao-Qiang,Miyaura, Norio
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p. 928 - 931
(2008/09/20)
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