New synthetic routes to the three isomeric tetranitrotoluenes 1-3 are described, including the previously unreported 2,3,4,5-tetranitrotoluene (1).Methods include peroxydisulfuric acid oxidation of trinitrotoluidines and hypophosphorous acid reduction of
Nielsen, Arnold T.,Christian, Stephen L.,Chafin, Andrew P.,Wilson, William S.
p. 1714 - 1718
(2007/10/02)
Synthesis of Polynitrodiazophenols
The formation of diazophenols by nitration of suitably substituted anilines and rearrangement of the nitroaromatic nitramines so formed is presented.The scope of the reaction is discussed, and a mechanism for the nitramine/diazophenol rearrangement is proposed which is consistent with 15N-labeling experiments.
Atkins, Ronald L.,Wilson, William S.
p. 2572 - 2578
(2007/10/02)
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