1026692-54-5Relevant articles and documents
A novel self-terminated Prins strategy for the synthesis of tetrahydropyran-4-one derivatives and their behaviour in Fisher indole synthesis
Reddy, B. V. Subba,Anjum, S. Rehana,Sridhar
, p. 75133 - 75137 (2016/08/24)
A novel self-terminated Prins strategy has been developed for the synthesis of 2-substituted tetrahydropyran-4-one derivatives through a condensation of 3-(phenylthio)but-3-en-1-ol with carbonyl compounds in the presence of 5 mol% of Sc(OTf)3 u
2,3-dichloro-5,6-dicyano-1,4-benzoquinone-catalyzed teactions employing MnO2 as a stoichiometric oxidant
Liu, Lei,Floreancig, Paul E.
supporting information; experimental part, p. 4686 - 4689 (2010/12/24)
Several oxidative reactions can be effected with MnO2 in the presence of substoichiometric quantities of DDQ. These transformations include oxidative cyclization, deprotection, and dehydrogenation reactions. The use of MnO2 as a terminal oxidant for DDQ-mediated reactions is attractive based on economical and environmental factors.
Mechanistic analysis of oxidative C-H cleavages using inter- and intramolecular kinetic isotope effects
Jung, Hyung Hoon,Floreancig, Paul E.
experimental part, p. 10830 - 10836 (2010/02/28)
A series of monodeuterated benzylic and allylic ethers were subjected to oxidative carbon-hydrogen bond cleavage to determine the impact of structural variation on intramolecular kinetic isotope effects in DDQ-mediated cyclization reactions. These values