102787-43-9

Basic information

• Product Name: Benzene, [[(1-ethyl-2-propenyl)oxy]methyl]-
• CAS NO: 102787-43-9
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 102787-43-9.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [[(1-ethyl-2-propenyl)oxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(1-ethyl-2-propenyl)oxy]methyl]-(102787-43-9)
• EPA Substance Registry System: Benzene, [[(1-ethyl-2-propenyl)oxy]methyl]-(102787-43-9)

Safety Data

• Hazardous Substances Data: 102787-43-9(Hazardous Substances Data)

Upstream product

• 616-25-1 1-Penten-3-ol 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 
• 909803-60-7 3-benzyloxypent-1-yne 
• 4187-86-4 pent-1-yn-3-ol 
• 1576-96-1 (E)-2-penten-1-ol 
• 100-51-6 benzyl alcohol 

Downstream Products

• 94371-17-2 (R)-5-((S)-1-Benzyloxy-propyl)-3-(2-methyl-[1,3]dioxolan-2-ylmethyl)-4,5-dihydro-isoxazole 
• 94371-19-4 (R)-5-((R)-1-Benzyloxy-propyl)-3-(2-methyl-[1,3]dioxolan-2-ylmethyl)-4,5-dihydro-isoxazole 
• 58927-85-8 (3Z)-1-phenyl-3-hexen-1-ol 
• 58927-86-9 (E)-1-Phenyl-3-hexen-1-ol 
• 89279-49-2 2-(benzyloxy)butanal 
• 1180481-14-4 C₂₀H₃₄OSi 

Relevant articles and documents

Highly selective hydrogenation of multiple carbon-carbon bonds promoted by nickel(0) nanoparticles

A new method for the highly stereoselective cis semihydrogenation of internal alkynes, semihydrogenation of terminal alkynes, reduction of dienes to alkenes, and reduction of alkynes and alkenes to alkanes is described based on in situ generated both Ni(0) nanoparticles and molecular hydrogen.

Highly stereoselective semihydrogenation of alkynes promoted by nickel(0) nanoparticles

A new method for the highly stereoselective cis-semihydrogenation of internal alkynes is described based on in situ generated Ni(0) nanoparticles and molecular hydrogen. This reduction system also allows the semihydrogenation of terminal alkynes.

The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex

A 1:1 mixture of [AuCl(IPr)] (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2- ylidine) and AgClO4 catalyzes the intermolecular dehydrative alkoxylation of primary and secondary allylic alcohols with aliphatic primary and secondary alcohols to for

Asymmetric Hetero-Diels-Alder Reaction of α-Alkoxy Aldehydes with Activated Dienes. The Scope of Lewis Acid Chelation-Controlled Cycloadditions

The cycloaddition reactions of various α-alkoxy aldehydes with 1,3-dimethoxy-1--1,3-butadiene (Brassard's diene, 2) were performed under the Lewis acid catalysis of Eu(hfc)3, magnesium dibromide, or diethylaluminum chloride.Moderate to high diastereoselectivities were observed with Eu(hfc)3 and magnesium dibromide.Evidence from reactions of Eu(hfc)3 and magnesium dibromide catalysis indicated a possible "chelation-control" pathway.Lewis acid catalysis from diethylaluminum chloride provides products with moderate to high diastereoselectivity.The mechanistic pathway with catalysis by diethylaluminum chloride was less clear.A possible mechanism based upon a "Cram" addition is considered.

Stereoselective Synthesis of Alcohols, XXII. E/Z-Selectivity on Addition of α-Substituted Allylboronates to Aldehydes

α-Heterosubstituted allylboronates 7 are prepared.Addition of 7 to aldehydes results in E/Z-isomeric homoallyl alcohols 13 and 14.The reasons for the predominant formation of the Z-isomer 14 are discussed.The Z-bromo olefins 16 and 20 obtained in this way serve as starting point for chain extension or formation of δ-lactones 21.