102910-30-5

Basic information

• Product Name: ALLYL-D5 ALCOHOL, 98 ATOM % D
• Synonyms: ALLYL-D5 ALCOHOL, 98 ATOM % D
• CAS NO: 102910-30-5
• Molecular Formula: C₃H₆O
• Molecular Weight: 63.10994889
• Product Categories: Alphabetical Listings;APesticides&Metabolites;Fungicides;LabeledPesticides;Others;Pesticides;Stable Isotopes
• Mol File: 102910-30-5.mol

Chemical Properties

• Melting Point: −129 °C(lit.)
• Boiling Point: 96-98 °C(lit.)
• Flash Point: 72 °F
• Appearance: /
• Density: 0.926 g/mL at 25 °C
• Refractive Index: n20/D 1.41(lit.)
• CAS DataBase Reference: ALLYL-D5 ALCOHOL, 98 ATOM % D(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL-D5 ALCOHOL, 98 ATOM % D(102910-30-5)
• EPA Substance Registry System: ALLYL-D5 ALCOHOL, 98 ATOM % D(102910-30-5)

Safety Data

• Hazard Codes: T+
• Statements: 50-10
• Safety Statements: 16-26-27-36/37/39-45-61
• RIDADR: UN 1098 6.1/PG 1
• WGK Germany: 3
• Hazardous Substances Data: 102910-30-5(Hazardous Substances Data)

Upstream product

• 920-42-3 dideuterioformic acid 
• 62502-71-0 [1,1,2,3,3-2H₅]glycerol 
• 64-18-6 formic acid 
• 56-81-5 glycerol 
• 182244-60-6 hexyl 3-deuteropropiolate 
• 3634-35-3 Propiolsaeure 

Downstream Products

• 185201-66-5 allyl-d5 4-methylbenzenesulfonate 

Relevant articles and documents

Synthesis of glycerol deuterated ether phospholipids

1,3-Dialkyl glycerophosphocholines deuterated on the glycerol moiety were synthesized starting either from propiolic acid to yield a pentadeuterated compound, or from epibromohydrin to give a monodueterated substance.

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

An efficient 1,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass-derived polyols (glycerol and erythritol) that results in the conversion of the 1,2-dihydroxy group to a carbon-carbon double bond.

Studies on thermal reactivity of β-(1,2-allenyl)butenolides and 2-allyl-3-allenylcyclohex-2-enones

A series of thermal pericyclic reactions of β-allenylfuranones have been studied. It was observed that β-allenylfuranones would undergo 1,5-hydrogen shift to afford a new type of trienes upon heating. Due to their high reactivity, these trienes would undergo subsequent pericyclic reactions based on the nature of the substituent group R: When R is an alkyl group, the intermediate 4a or 4b would undergo a further 1,7-hydrogen shift to afford a more stable conjugated triene 3; with R being phenyl or cyclopropyl group, the 1,7-hydrogen shift was inhibited and the 4-type conjugated triene would form a six-membered ring 5 via 6π-electrocyclization. Interestingly, introducing another C=C double bond into the triene intermediate (R = CH=CH2), the 18-type intermediate would undergo 8π-electrocyclization reaction to form an eight-membered ring. Such a transformation was also observed with 2-allyl-3-allenylcyclohex-2-enones. The deuterium-labeling mechanistic studies show that the alkyl groups at the allenyl moiety of 1 participated in the isomerization process via 1,7-hydrogen shifts between 18 A, 20A, and 29 A.

DETERMINATION OF KIDNEY FUNCTION

The present invention provides an isotopically labelled marker of formula (I): where R1 -R5 are as defined herein; characterised in that one or more of the H, N, C or O atoms in the compound of formula (I) is replaced with one or more of2H, 13C, 15N, 17O or 18O respectively, methods for using the inventive marker in detecting the presence or absence of a filtration marker in a sample, measuring the rate of glomerular filtration in a subject and/or diagnosing kidney disease and/or damage in a subject.

Anwendung der Perdeuteroallyl Schutz-Gruppe

Facile and straightforward transformations of propynoic acid into perdeuterated allyl bromide are described.The advantage of a pentadeuteroallyl protection for the 1H-N.M.R. structure elucidation of complex carbohydrate derivatives is demonstrated in the