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64-18-6 Usage

InChI:InChI=1/CH2O2/c2-1-3/h1H,(H,2,3)

64-18-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (F0513)  Formic Acid   64-18-6 300mL 170.00CNY Detail
Alfa Aesar (36617)  Formic acid, ACS, 96+%    64-18-6 500g 595.0CNY Detail
Alfa Aesar (36617)  Formic acid, ACS, 96+%    64-18-6 2kg 881.0CNY Detail
Alfa Aesar (36617)  Formic acid, ACS, 96+%    64-18-6 *4x500g 1235.0CNY Detail
Alfa Aesar (36504)  Formic acid, ACS, 88+%    64-18-6 500ml 560.0CNY Detail
Alfa Aesar (36504)  Formic acid, ACS, 88+%    64-18-6 2L 1145.0CNY Detail
Alfa Aesar (36504)  Formic acid, ACS, 88+%    64-18-6 *4x500ml 1443.0CNY Detail
Alfa Aesar (L17434)  Formic acid, 85%    64-18-6 1000g 313.0CNY Detail
Alfa Aesar (L17434)  Formic acid, 85%    64-18-6 2500g 617.0CNY Detail
Alfa Aesar (A13285)  Formic acid, 97%    64-18-6 500g 288.0CNY Detail
Alfa Aesar (A13285)  Formic acid, 97%    64-18-6 2500g 775.0CNY Detail
Alfa Aesar (A13285)  Formic acid, 97%    64-18-6 10000g 1666.0CNY Detail

64-18-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name formic acid

1.2 Other means of identification

Product number -
Other names formic

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Preservatives and Antioxidants;Processing Aids and Additives
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64-18-6 SDS

64-18-6Synthetic route

carbon dioxide
124-38-9

carbon dioxide

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With chlorotris(sodium 3-sulfonatophenyldiphenylphosphine)rhodium(I); hydrogen; sodium formate In water at 50℃; under 75007.5 Torr; for 20h; Inert atmosphere;100%
With sodium hydrogencarbonate In water for 18h; Reagent/catalyst; Electrochemical reaction;93.6%
Stage #1: carbon dioxide With phenylsilane In N,N-dimethyl acetamide at 50℃; under 22502.3 Torr; for 4h; pH=Ca. 1.2; Autoclave; Green chemistry;
Stage #2: With water In N,N-dimethyl acetamide at 100℃; for 0.25h; Pressure; Temperature; Reagent/catalyst; Time; Green chemistry;
91%
methanol
67-56-1

methanol

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
Stage #1: methanol With oxygen; nickel dichloride In water at 20℃; for 0.166667h; Flow reactor;
Stage #2: With copper(II) sulfate In water at 55℃; for 0.166667h; Flow reactor;
98%
With sodium hydroxide; potassium hexacyanoferrate(III); iridium(III) chloride at 35℃; Rate constant; Thermodynamic data; ΔE, ΔS(excit.), ΔF(excit.);
With dipotassium peroxodisulfate In water at 45℃; Kinetics; Rate constant; Thermodynamic data; mechanism, concentration, temperature, overall energy of activation;
1-ethenyl-4-methylbenzene
622-97-9

1-ethenyl-4-methylbenzene

A

formic acid
64-18-6

formic acid

B

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate; 2-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)-6-((4R,5R)-1-((4-(tert-butyl)phenyl)sulfonyl)-4,5-diphenylimidazolidin-2-yl)pyridine; oxygen at 70℃; under 760.051 Torr; for 6h; Solvent; Green chemistry;A n/a
B 96%
2-((tert-butyl-diphenyl-silanyloxy)methyl)-2-methyl-malonaldehyde

2-((tert-butyl-diphenyl-silanyloxy)methyl)-2-methyl-malonaldehyde

A

formic acid
64-18-6

formic acid

B

3-(tert-butyldiphenylsilanyloxy)-2-methylpropionic acid
820963-51-7

3-(tert-butyldiphenylsilanyloxy)-2-methylpropionic acid

Conditions
ConditionsYield
With camphor-10-sulfonic acid; dihydrogen peroxide In chloroform-d1A 50%
B 96%
formic acid 2-formyloxy-1-methylpropyl ester
56153-29-8

formic acid 2-formyloxy-1-methylpropyl ester

A

formic acid
64-18-6

formic acid

B

trans-2-Butene
624-64-6

trans-2-Butene

C

buta-1,3-diene
106-99-0

buta-1,3-diene

D

butanone
78-93-3

butanone

Conditions
ConditionsYield
at 500℃; for 5h; Mechanism; Inert atmosphere; Flow reactor; Pyrolysis; chemoselective reaction;A 20%
B n/a
C 94%
D n/a
styrene
292638-84-7

styrene

A

formaldehyd
50-00-0

formaldehyd

B

formic acid
64-18-6

formic acid

C

benzaldehyde
100-52-7

benzaldehyde

D

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With pyridine; ozone at 20℃; for 1.16667h; Oxidation; ozonolysis;A 2%
B 2.4%
C 2.6%
D 93%
2 HCOOH/NHex3 adduct

2 HCOOH/NHex3 adduct

A

formic acid
64-18-6

formic acid

B

tri-n-hexylamine
102-86-3

tri-n-hexylamine

Conditions
ConditionsYield
at 160℃; under 99.76 Torr;A 92%
B n/a
cerium (IV) ammonium nitrate

cerium (IV) ammonium nitrate

pentamine methylmalonatocobalt(III)

pentamine methylmalonatocobalt(III)

A

formic acid
64-18-6

formic acid

B

carbon dioxide
124-38-9

carbon dioxide

C

cobalt(II)

cobalt(II)

D

cerium(III) ion

cerium(III) ion

Conditions
ConditionsYield
In perchloric acid; water Kinetics; react. at 30 +/- 0.2°C; detection by spectrophotometry;A 90%
B n/a
C >99
D n/a
cerium (IV) ammonium nitrate

cerium (IV) ammonium nitrate

pentamine malonatocobalt(III)

pentamine malonatocobalt(III)

A

formic acid
64-18-6

formic acid

B

carbon dioxide
124-38-9

carbon dioxide

C

cobalt(II)

cobalt(II)

D

cerium(III) ion

cerium(III) ion

Conditions
ConditionsYield
In perchloric acid; water Kinetics; react. at 30 +/- 0.2°C; detection by spectrophotometry;A 90%
B n/a
C >99
D n/a
dimethyl(phenyl)silyl formate

dimethyl(phenyl)silyl formate

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With water at 20℃; for 0.5h;90%
syringic aldehyde
134-96-3

syringic aldehyde

A

formic acid
64-18-6

formic acid

B

2,6-dimethoxy-1,4-hydroquinone
15233-65-5

2,6-dimethoxy-1,4-hydroquinone

Conditions
ConditionsYield
Stage #1: syringic aldehyde With sodium percarbonate In tetrahydrofuran; water at 25℃; Dakin Phenol Oxidation; Inert atmosphere;
Stage #2: With hydrogenchloride In tetrahydrofuran; water pH=1; Inert atmosphere;
A n/a
B 90%
6-methyl-6-phenyl-3-(1-phenylethyl)-5-(m-toluidino)-1,2,4-trioxan
76182-15-5

6-methyl-6-phenyl-3-(1-phenylethyl)-5-(m-toluidino)-1,2,4-trioxan

A

formic acid
64-18-6

formic acid

B

2-Phenylpropanal
34713-70-7

2-Phenylpropanal

C

acetophenone
98-86-2

acetophenone

D

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

Conditions
ConditionsYield
With hydrogenchloride In ethanol for 0.0833333h; Ambient temperature; Further byproducts given;A 58%
B 69%
C 89%
D 75%
triethylsilyl formate
18296-01-0

triethylsilyl formate

A

formic acid
64-18-6

formic acid

B

Triethylsilanol
597-52-4

Triethylsilanol

Conditions
ConditionsYield
In water at 20℃; for 0.333333h; Schlenk technique; Inert atmosphere; Glovebox;A 88%
B n/a
sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
Stage #1: sodium hydrogencarbonate With hydrogen In water at 200℃; under 45004.5 Torr; for 4h; Autoclave;
Stage #2: Pressure; Reagent/catalyst;
86.1%
With nickel; hydrazine hydrate In water at 300℃; for 2h; Reagent/catalyst; Green chemistry;50%
With sodium chloride at 40℃; for 2h; Irradiation; Halobacterium halobium MMT22; Yield given;
glycolic Acid
79-14-1

glycolic Acid

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With potassium bromate; ruthenium trichloride; perchloric acid at 39.85℃; Kinetics; Further Variations:; Reagents; Temperatures; Oxidation;86%
With phosphovanadomolybdic acid; oxygen In water at 150℃; under 15001.5 Torr; for 3h;73.9%
With aluminium(III) triflate; dihydrogen peroxide In acetonitrile at 70℃; for 12h;63.1%
dihydroxyacetone
96-26-4

dihydroxyacetone

A

formic acid
64-18-6

formic acid

B

glycolic Acid
79-14-1

glycolic Acid

Conditions
ConditionsYield
With dihydrogen peroxide In neat (no solvent) at 25℃; for 24h; Catalytic behavior; Reagent/catalyst;A n/a
B 86%
With oxygen; vanadia In water at 79.84℃; under 2250.23 Torr; for 1h; Autoclave;A 14 %Chromat.
B 13 %Chromat.
Methyl formate
107-31-3

Methyl formate

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With 2,6-dimethylpyridine; water at 120℃; under 9000.9 Torr;85%
With sulfuric acid Hydrolysis;
With water; N-cyclohexyl-cyclohexanamine at 130℃; Equilibrium constant; Reagent/catalyst;
Glyoxal
131543-46-9

Glyoxal

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With phosphovanadomolybdic acid; oxygen In water at 150℃; under 15001.5 Torr; for 3h;84.3%
With dihydrogen peroxide; sodium molybdate; mercury(II) diacetate In 1,4-dioxane; water at 25℃; for 0.5h; Yield given;
With TiClO4 at 39.9℃; Rate constant; Kinetics; Thermodynamic data; E(excit.), ΔH(excit.), ΔS(excit.); var. temp.;
With sodium vanadate; sulfuric acid; oxygen In water at 160℃; under 22502.3 Torr; for 0.0166667h; Autoclave;
With H(1+)*Mo11O40PV(4-)*3C7H13N2O3S(1+); oxygen In water at 180℃; under 7500.75 Torr; for 1h; Autoclave;74.2 %Chromat.
potassium hydrogencarbonate
298-14-6

potassium hydrogencarbonate

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With hydrogen In water at 200℃; under 45004.5 Torr; for 4h; Autoclave;83.7%
With [{Ir(pentamethylcyclopentadienyl)(Cl)}2(4,4',6,6'-tetrahydroxybipyrimidine)](Cl2); hydrogen In water at 50℃; under 30003 Torr; for 8h; Catalytic behavior; Reagent/catalyst; Pressure; Time; Temperature;
With hydrogen carbonate reductase; hydrogen under 750.075 Torr; Kinetics; Reagent/catalyst; Enzymatic reaction;
dihydroxyacetone
96-26-4

dihydroxyacetone

A

formic acid
64-18-6

formic acid

B

glycolic Acid
79-14-1

glycolic Acid

Conditions
ConditionsYield
With dihydrogen peroxide In neat (no solvent) at 25℃; for 24h; Catalytic behavior; Reagent/catalyst;A n/a
B 86%
With oxygen; vanadia In water at 79.84℃; under 2250.23 Torr; for 1h; Autoclave;A 14 %Chromat.
B 13 %Chromat.
With iron hydroxide oxide; manganese(IV) oxide; dihydrogen peroxide In water at 25℃; for 24h; Reagent/catalyst; Autoclave;
cellulose

cellulose

A

formic acid
64-18-6

formic acid

B

levulinic acid
123-76-2

levulinic acid

Conditions
ConditionsYield
With hydrogenchloride; water at 199.84℃; for 0.166667h; Concentration; Temperature; Time;A 83%
B 43%
With water at 185 - 205℃; for 0.420833h; Product distribution / selectivity; Acidic conditions;A 82%
B n/a
With 5-methyl-dihydro-furan-2-one at 159.84℃; for 16h;A 20%
B 69%
3-methyl-butan-2-one
563-80-4

3-methyl-butan-2-one

A

formic acid
64-18-6

formic acid

B

isobutyric Acid
79-31-2

isobutyric Acid

Conditions
ConditionsYield
With perchloric acid; bromamine T In water at 35 - 40℃; Kinetics; Mechanism; Thermodynamic data; ΔH and ΔS; var. solv.: D2O;A 82%
B 82%
With perchloric acid; mercury(II) diacetate; N-bromoacetamide In water at 30℃; Kinetics; Mechanism; effect of the concentrations of NBA, MIK, acid and Hg(OAc)2; effect of the ionic strength; D2O isotopic effect; further temperatures;
D-Glucose
2280-44-6

D-Glucose

A

5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

B

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With phosphoric acid immobilized anatase TiO2 In tetrahydrofuran; water at 119.84℃; for 2h; Sealed tube; Green chemistry;A 81.2%
B 10.5%
With dihydrogen peroxide In water at 200℃; for 1h; pH=5.4;A 11.55%
B 5.68%
alpha-D-glucopyranose
492-62-6

alpha-D-glucopyranose

A

5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

B

formic acid
64-18-6

formic acid

C

levulinic acid
123-76-2

levulinic acid

D

levoglucosan
498-07-7

levoglucosan

Conditions
ConditionsYield
With 15 wtpercent phosphate impregnated titania In water; butan-1-ol at 175℃; under 22502.3 Torr; for 3h; Catalytic behavior; Temperature; Inert atmosphere; Autoclave;A 81%
B n/a
C n/a
D n/a
Glycolaldehyde
141-46-8

Glycolaldehyde

A

formic acid
64-18-6

formic acid

B

glycolic Acid
79-14-1

glycolic Acid

C

Glyoxal
131543-46-9

Glyoxal

D

carbon dioxide
124-38-9

carbon dioxide

E

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With water; oxygen at 90℃; under 7500.75 Torr; for 8h; Catalytic behavior; Mechanism; Temperature; Pressure; Time; Reagent/catalyst;A 80.5%
B 4.2%
C 6.2%
D 2.6%
E 0.3%
D-Arabinose
10323-20-3

D-Arabinose

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With dihydrogen peroxide In ethanol; water at 69.84℃; for 5h; Inert atmosphere; Schlenk technique; chemoselective reaction;79.7%
D-xylose
58-86-6

D-xylose

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With dihydrogen peroxide In ethanol; water at 69.84℃; for 5h; Inert atmosphere; Schlenk technique; chemoselective reaction;79.6%
With phosphovanadomolybdic acid; oxygen In water at 180℃; under 15001.5 Torr; for 3h;33.1%
With sodium chloride In water at 189.84℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere;9.6%
With sodium vanadate; sulfuric acid; oxygen In water at 160℃; under 22502.3 Torr; for 0.0166667h; Autoclave;
With C13H16ClN3O2Pd; dihydrogen peroxide; sodium hydroxide In water at 25℃; for 16h; Catalytic behavior;
sodium formate
141-53-7

sodium formate

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With sulfuric acid79%
With water Electrolysis.Mehrkammersystem mit Kammerwaenden aus semipermeablen Ionenaustauschern;
With sulfuric acid; sulfur trioxide
1-octen-3-ol
3391-86-4

1-octen-3-ol

A

formic acid
64-18-6

formic acid

B

hexanoic acid
142-62-1

hexanoic acid

C

valeric acid
109-52-4

valeric acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI) In benzene at 70℃; for 48h; Product distribution; other reaction times, other catalysts, other allylic alcohols and olefins as substrates;A n/a
B 79%
C 6%
3β-formyloxy-5αH-cholestane
10437-24-8

3β-formyloxy-5αH-cholestane

A

formic acid
64-18-6

formic acid

B

cholestane
481-21-0

cholestane

C

Cholestanol
80-97-7

Cholestanol

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide; water for 5h; Irradiation;A n/a
B 79%
C 19%
phenylacetylene
536-74-3

phenylacetylene

A

formic acid
64-18-6

formic acid

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With iodopentafluorobenzene bis(trifluoroacetate); water In benzene Product distribution; Heating; other alkynes or α-hydroxy-p-nitroacetophenone;A n/a
B 79%
piperidine
110-89-4

piperidine

formic acid
64-18-6

formic acid

N-Formylpiperidine
2591-86-8

N-Formylpiperidine

Conditions
ConditionsYield
With cyano-hydroxyimino-acetic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester; sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water at 20℃; for 3h; Reagent/catalyst; Solvent;100%
With aminoproplylated mesoporous SBA-15 silica at 40℃; for 0.25h; Neat (no solvent); chemoselective reaction;95%
With NH2-MIL-53 at 50℃; for 0.333333h;95%
morpholine
110-91-8

morpholine

formic acid
64-18-6

formic acid

4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

Conditions
ConditionsYield
With cyano-hydroxyimino-acetic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester; sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water at 20℃; for 3h; Reagent/catalyst; Solvent;100%
In butan-1-ol at 120℃; Solvent; Temperature;99.35%
In ethanol at 140℃; for 24h; Solvent; Autoclave;98%
formic acid
64-18-6

formic acid

n-Octylamine
111-86-4

n-Octylamine

N-octylformamide
6282-06-0

N-octylformamide

Conditions
ConditionsYield
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent;100%
formic acid
64-18-6

formic acid

1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

1-dodecanyl formate
28303-42-6

1-dodecanyl formate

Conditions
ConditionsYield
toluene-4-sulfonic acid at 85℃; for 4h; Esterification;100%
With 2-methyl-1-butylimidazolium trifluoroacetate In neat (no solvent) at 70℃; for 1h;96%
Stage #1: formic acid With acetic anhydride at 40℃; for 2h;
Stage #2: 1-dodecyl alcohol at 0 - 20℃; for 15.25h;
94%
With hydrogenchloride
formic acid
64-18-6

formic acid

dehydroepiandrosterone
53-43-0

dehydroepiandrosterone

3β-formyl-oxy-5-androsten-17-one
29163-23-3

3β-formyl-oxy-5-androsten-17-one

Conditions
ConditionsYield
In water for 19h;100%
at 20 - 25℃; for 4h;100%
for 5h; Reflux;89.3%
for 5h; Reflux;
formic acid
64-18-6

formic acid

2,3-diaminochlorobenzene
21745-41-5

2,3-diaminochlorobenzene

4-chloro-1H-1,3-benzodiazole
16931-35-4

4-chloro-1H-1,3-benzodiazole

Conditions
ConditionsYield
In water at 100℃; for 3h; Phillips cyclization;100%
In water at 100℃; for 3h;84.1%
formic acid
64-18-6

formic acid

Phenylalanine
150-30-1

Phenylalanine

N-formyl-phenylalanine
4289-95-6

N-formyl-phenylalanine

Conditions
ConditionsYield
With acetic anhydride at 20℃; for 1h;100%
With acetic anhydride at 20℃; for 19h;87%
In N,N-dimethyl-formamide for 0.166667h; Heating;81%
formic acid
64-18-6

formic acid

methanol
67-56-1

methanol

Conditions
ConditionsYield
With water In aq. phosphate buffer at 20℃; for 1h; pH=7.4; Catalytic behavior; Reagent/catalyst; Electrolysis; Inert atmosphere; Enzymatic reaction;100%
With cobalt(III) acetylacetonate; hydrogen; bis(trifluoromethanesulfonyl)amide; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In tetrahydrofuran; ethanol at 100℃; under 52505.3 Torr; for 24h; Autoclave; Inert atmosphere;59%
With C36H54IrN2P2(1+)*C24H20B(1-); hydrogen; sodium hydride In ethanol; toluene at 180℃; under 7500.75 - 45004.5 Torr; for 18h; Autoclave;31%
formic acid
64-18-6

formic acid

acetic anhydride
108-24-7

acetic anhydride

Acetic formic anhydride
2258-42-6

Acetic formic anhydride

Conditions
ConditionsYield
at 60℃; for 1h; Inert atmosphere;100%
at 0 - 60℃; for 3.5h;78%
at 50℃; Fraktionierung im Vakuum;
formic acid
64-18-6

formic acid

4-chloro-aniline
106-47-8

4-chloro-aniline

N-(4-chlorophenyl)formamide
2617-79-0

N-(4-chlorophenyl)formamide

Conditions
ConditionsYield
In toluene Reflux;100%
With sodium formate at 20℃; for 2h; Neat (no solvent);98%
With TiO2-SO4(2-) In acetonitrile at 20℃; for 6h;98.3%
formic acid
64-18-6

formic acid

4-methoxy-aniline
104-94-9

4-methoxy-aniline

4-methoxyformanilide
5470-34-8

4-methoxyformanilide

Conditions
ConditionsYield
In toluene Reflux;100%
With sodium formate at 20℃; for 3h; Neat (no solvent);99%
With TiO2-SO4(2-) In acetonitrile at 20℃; for 4h;99%
formic acid
64-18-6

formic acid

2-(3,4-dimethoxyphenyl)-ethylamine
120-20-7

2-(3,4-dimethoxyphenyl)-ethylamine

N-[2-(3,4-dimethoxyphenyl)ethyl]formamide
14301-36-1

N-[2-(3,4-dimethoxyphenyl)ethyl]formamide

Conditions
ConditionsYield
With acetic anhydride 1.) 60 deg C, 30 min, 2.) 20 deg C, overnight;100%
With 4-methyl-morpholine; dmap; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In dichloromethane at 35℃; for 0.05h; microwave irradiation;98%
In dichloromethane at 80℃; for 8h;95%
formic acid
64-18-6

formic acid

phenethylamine
64-04-0

phenethylamine

N-(2-phenylethyl)formamide
23069-99-0

N-(2-phenylethyl)formamide

Conditions
ConditionsYield
Stage #1: formic acid With acetic acid at 25℃; for 1h;
Stage #2: phenethylamine at 0 - 25℃;
100%
With sulfated tungstate at 70℃; for 0.166667h; Neat (no solvent);98%
With pyridine; diisopropyl-carbodiimide at 20℃; for 72h;15%
formic acid
64-18-6

formic acid

4-Chloro-1,2-phenylenediamine
95-83-0

4-Chloro-1,2-phenylenediamine

5-chloro-1H-benzimidazole
4887-82-5

5-chloro-1H-benzimidazole

Conditions
ConditionsYield
With hydrogenchloride In water for 3h; Reflux;100%
at 110℃; for 4h;95%
With tetrabutyl-ammonium chloride In water; toluene at 160℃; for 0.25h; Microwave irradiation;89%
formic acid
64-18-6

formic acid

aniline
62-53-3

aniline

Formanilid
103-70-8

Formanilid

Conditions
ConditionsYield
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent;100%
With zinc(II) oxide at 70℃; for 0.166667h;99%
Stage #1: formic acid With silica gel at 20℃; for 0.0166667h;
Stage #2: aniline With silica gel at 110℃; for 0.05h;
99%
formic acid
64-18-6

formic acid

4-Nitrophenylene-1,2-diamine
99-56-9

4-Nitrophenylene-1,2-diamine

5-nitrobenzimidazole
94-52-0

5-nitrobenzimidazole

Conditions
ConditionsYield
With hydrogenchloride In water for 8h; Reflux;100%
With tetrabutyl-ammonium chloride In water; toluene at 160℃; for 0.2h; Microwave irradiation;90%
With chloro-trimethyl-silane In water; N,N-dimethyl-formamide at 120℃; for 0.2h; Microwave irradiation;90%
formic acid
64-18-6

formic acid

glycine
56-40-6

glycine

formylglycine
2491-15-8

formylglycine

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 110℃; for 0.666667h;100%
In N,N-dimethyl-formamide at 153℃; for 0.333333h; futher solvents, further temperatures, further reaction times;97%
Stage #1: formic acid With acetic anhydride at 45℃; for 1h; Inert atmosphere;
Stage #2: glycine at 20℃; for 72h; Inert atmosphere;
93%
formic acid
64-18-6

formic acid

2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

2,6-dimethylformanilide
607-92-1

2,6-dimethylformanilide

Conditions
ConditionsYield
In toluene Reflux;100%
In toluene Reflux;100%
In toluene Reflux;100%
formic acid
64-18-6

formic acid

4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

4-methoxy-, benzenemethanol, formate
122-91-8

4-methoxy-, benzenemethanol, formate

Conditions
ConditionsYield
Stage #1: formic acid With silica gel at 20℃; for 0.0166667h;
Stage #2: 4-Methoxybenzyl alcohol With silica gel at 110℃; for 0.0166667h;
100%
With aminopropylated mesoporous SBA-15 silica at 40℃; for 0.0833333h; Neat (no solvent); chemoselective reaction;95%
With iodine at 20℃; for 0.116667h; neat (no solvent);94%
formic acid
64-18-6

formic acid

benzylamine
100-46-9

benzylamine

N-benzylformamide
6343-54-0

N-benzylformamide

Conditions
ConditionsYield
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent;100%
With 4-methyl-morpholine; dmap; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In dichloromethane at 35℃; for 0.1h; microwave irradiation;99%
With sulfated tungstate at 70℃; for 0.166667h; Neat (no solvent);99%
formic acid
64-18-6

formic acid

4-bromo-aniline
106-40-1

4-bromo-aniline

N-(4-bromophenyl)formamide
2617-78-9

N-(4-bromophenyl)formamide

Conditions
ConditionsYield
In toluene Reflux;100%
With sodium formate at 20℃; for 2.75h; Neat (no solvent);99%
With zinc(II) oxide at 70℃; for 0.333333h;98%
formic acid
64-18-6

formic acid

4-Bromo-benzene-1,2-diamine
1575-37-7

4-Bromo-benzene-1,2-diamine

5-bromo-1H-benzo[d]imidazole
4887-88-1

5-bromo-1H-benzo[d]imidazole

Conditions
ConditionsYield
at 100℃;100%
With hydrogenchloride In water for 3h; Reflux;97.5%
for 2h; Reflux;85%
With hydrogenchloride
Stage #1: formic acid; 4-Bromo-benzene-1,2-diamine for 2h; Reflux;
Stage #2: With sodium hydroxide In water at 20℃;
formic acid
64-18-6

formic acid

methyl α-chloro-α-phenylbenzeneacetate
54311-64-7

methyl α-chloro-α-phenylbenzeneacetate

methyl (formyloxy)diphenylacetate
133217-21-7

methyl (formyloxy)diphenylacetate

Conditions
ConditionsYield
With sodium formate for 4h; Ambient temperature;100%
With sodium formate In N,N-dimethyl-formamide for 3h; Ambient temperature;96%
formic acid
64-18-6

formic acid

2-iodophenylamine
615-43-0

2-iodophenylamine

N-formyl-2-iodoaniline
10113-39-0

N-formyl-2-iodoaniline

Conditions
ConditionsYield
Stage #1: formic acid With acetic anhydride In dichloromethane at 20℃; for 0.166667h;
Stage #2: 2-iodophenylamine In dichloromethane at 20℃;
100%
In water; toluene at 110℃; for 4h;99%
Stage #1: formic acid With acetic anhydride at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: 2-iodophenylamine In dichloromethane at 20℃; for 2h; Inert atmosphere;
98%
formic acid
64-18-6

formic acid

tetra(n-butyl)ammonium hydroxide
2052-49-5

tetra(n-butyl)ammonium hydroxide

tetra(n-butyl)ammonium formate
35733-58-5

tetra(n-butyl)ammonium formate

Conditions
ConditionsYield
In water pH=Ca. 8.45; Glovebox;100%
In methanol; water at 20 - 60℃;99%
In methanol at 20℃; for 2h; Inert atmosphere;85%
formic acid
64-18-6

formic acid

4-(2-aminoethyl)-1-(phenylmethyl)piperidine
86945-25-7

4-(2-aminoethyl)-1-(phenylmethyl)piperidine

1-benzyl-4-<2-(N-formylamino)ethyl>piperidine
144319-70-0

1-benzyl-4-<2-(N-formylamino)ethyl>piperidine

Conditions
ConditionsYield
With acetic anhydride100%
at 100℃; for 6h;38%
formic acid
64-18-6

formic acid

1-(4-hydroxy-phenyl)-piperazine dihydrobromide
38869-37-3

1-(4-hydroxy-phenyl)-piperazine dihydrobromide

1-Formyl-4-(4-hydroxyphenyl)piperazine
112190-13-3

1-Formyl-4-(4-hydroxyphenyl)piperazine

Conditions
ConditionsYield
With sodium carbonate In water; toluene for 18h; Heating;100%
formic acid
64-18-6

formic acid

1-(2,2-dimethyl-3-but-enyl)-5-hydroxy-2-pyrrolid-one
84665-97-4

1-(2,2-dimethyl-3-but-enyl)-5-hydroxy-2-pyrrolid-one

rel-(6R,7aS)-6-<2-(formyloxy)prop-2-yl>hexahydro-3H-pyrrolizin-3-one
84665-98-5, 94162-37-5

rel-(6R,7aS)-6-<2-(formyloxy)prop-2-yl>hexahydro-3H-pyrrolizin-3-one

Conditions
ConditionsYield
for 0.0833333h; Ambient temperature;100%
at 40℃; for 0.0833333h;0.462 g
formic acid
64-18-6

formic acid

shinjulactone C
82470-74-4, 130195-55-0

shinjulactone C

20-O-formylshinjulactone

20-O-formylshinjulactone

Conditions
ConditionsYield
for 2h; Ambient temperature;100%
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