104197-23-1Relevant articles and documents
Further Mass Spectral Studies of Flavones
Guidugli, F. H.,Ardanaz, C. E.,Kavka, J.,Garibay, M. E.,Joseph-Nathan, P.
, p. 117 - 124 (1986)
Further evidence supporting the structure of the + ion found in the mass spectrum of flavone as being the + species was obtained by comparison of linked scan measurements performed in flavone, 3-deuteroflavone, 5,6,7,8-tetradeuteroflavone, 2',3',4',5',6'-pentadeuteroflavone and dibenzo-β-tropolone.This fragmentation process has also been demonstrated in the case of 3-methoxyflavone by high-resolution measurements, deuterium labelling, metastable decompositions and evaluation of the subspectra of 9-methoxyfluorenol, fluorenone and biphenylene.The structure of the ion at m/z 181 in the spectrum of flavone was found to be the + species.
Ruthenium(II)-Catalyzed Synthesis of Spirobenzofuranones by a Decarbonylative Annulation Reaction
Kaishap, Partha P.,Duarah, Gauri,Sarma, Bipul,Chetia, Dipak,Gogoi, Sanjib
, p. 456 - 460 (2018/02/21)
The first decarbonylative insertion of an alkyne through C?H/C?C activation of six-membered compounds is reported. The Ru-catalyzed reaction of 3-hydroxy-2-phenyl-chromones with alkynes works most efficiently in the presence of the ligand PPh3 to provide spiro-indenebenzofuranones. Unlike previously reported metal-catalyzed decarbonylative annulation reactions, in the present decarbonylative annulation reaction, the annulation occurs before extrusion of carbon monoxide.