104581-09-1

Basic information

• Product Name: 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE
• Synonyms: 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE;VITAS-BB TBB000200
• CAS NO: 104581-09-1
• Molecular Formula: C₂₁H₁₄ClN₃
• Molecular Weight: 343.81
• Mol File: 104581-09-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE(CAS DataBase Reference)
• NIST Chemistry Reference: 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE(104581-09-1)
• EPA Substance Registry System: 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE(104581-09-1)

Safety Data

• Hazardous Substances Data: 104581-09-1(Hazardous Substances Data)

Upstream product

• 3111-60-2 2-[1-(4-chlorophenyl)ethylidene]malononitrile 
• 2826-25-7 2-(4-methylbenzylidene)malononitrile 
• 2826-26-8 2-(4-methoxyphenylmethylene)malononitrile 
• 19672-63-0 (2E)-1-(4-chlorophenyl)-3-(4-methylphenyl)prop-2-en-1-one 
• 2700-22-3 Benzylidenemalononitrile 
• 1867-38-5 4-chlorobenzylidenemalonodinitrile 
• 104-87-0 4-methyl-benzaldehyde 
• 99-91-2 para-chloroacetophenone 
• 109-77-3 malononitrile 

Relevant articles and documents

CeO2 nanoparticles: an efficient and robust catalyst for the synthesis of 2-amino-4,6-diarylbenzene-1,3-dicarbonitriles

CeO2 nanoparticles as an efficient catalyst have been used for the preparation of 2-amino-4,6-diarylbenzene-1,3-dicarbonitriles by the multi-component condensation reaction of aldehydes, acetophenones, and malononitrile in good to excellent yields, short reaction times, mild reaction conditions, and the employment of a cost-effective catalyst. Graphical abstract: [Figure not available: see fulltext.]

Efficient one-pot synthesis of 2-amino-4,6-diarylbenzene-1,3-dicarbonitrile under solvent-free conditions

A facile parallel synthesis of 2-amino-4,6-diarylbenzene-1,3-dicarbonitrile derivatives via a one-pot reaction of aromatic aldehydes, aromatic ketone, and malononitrile under solvent-free conditions has been developed. This new protocol has the advantages of shorter time, higher yields, lower cost, and environmental friendliness. Copyright Taylor & Francis Group, LLC.

Multicomponent synthesis of 3,5-diaryl-2,6-dicyanoanilines under thermal solvent-free conditions

A facile parallel synthesis of 3,5-diaryl-2,6-dicyanoanilines via three-component reaction of aryl aldehydes, acetophenone derivatives, and malononitrile under thermal green solvent-free conditions in the presence of potassium carbonate and also potassium bicarbonate without using any hazardous materials is described.

A rapid one-pot synthesis of 2,4,6-triaryl-3-aroyl-4-hydroxy-1,1-cyclohexanedicarbonitriles and 2-aminoisophthalonitriles under microwave activation

Ylidenemalononitriles 1 react with a variety of 1,3-diaryl-2-propen-1-ones 2 at ambient temperature and pressure under microwave activation to yield functionalised cyclohexanedicarbonitriles 3 and 2-aminoisophthalonitriles 4 in good yields.

ELIMINATION OF THE NITRILE GROUP FROM o-AMINONITRILES-IV; A NEW AND EFFICIENT SYNTHESIS OF 3,5-DIARYLAMINOBENZENES FROM ARYLIDENEMALONODINITRILES AND 1-ARYLETHYLIDENEMALONODINITRILES

A synthesis of a variety of 5'-amino-m-terphenyls (6) and 3,5-diarylaminobenzenes through an efficient elimination of cyano groups from 5'-amino-4',6'-dicyano-m-terphenyls (4) using sodium hydroxide in ethanol at 220 deg, is described.The starting o-amino