104770-18-5

Basic information

• Product Name: ETHYL 3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLATE HYDROCHLORIDE
• Synonyms: ETHYL 3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLATE HYDROCHLORIDE;DIEXO-3-AMINO-BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLIC ACID ETHYL ESTER HYDROCHLORIDE;Ethyl3-exo-aminobicyclo[2.2.1]hept-5-ene-2-exo-carboxylateHCl;Ethyl 3-exo-aminobicyclo[2.2.1]hept-5-ene-2-exo-carboxylate hydrochloride,99%;(1R,2R,3S,4S)-ethyl 3-aminobicyclo[2.2.1]hept-5-ene-2-carboxylate hydrochloride
• CAS NO: 104770-18-5
• Molecular Formula: C₁₀H₁₅NO₂*ClH
• Molecular Weight: 217.69
• Mol File: 104770-18-5.mol

Chemical Properties

• Melting Point: 129-132 °C
• Appearance: White to light beige/Fine Crystalline Powder
• CAS DataBase Reference: ETHYL 3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLATE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLATE HYDROCHLORIDE(104770-18-5)
• EPA Substance Registry System: ETHYL 3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLATE HYDROCHLORIDE(104770-18-5)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 104770-18-5(Hazardous Substances Data)

Usage

Chemical Properties

white to light beige fine crystalline powder

InChI:InChI=1/C10H15NO2.ClH/c1-2-13-10(12)8-6-3-4-7(5-6)9(8)11;/h3-4,6-9H,2,5,11H2,1H3;1H/t6-,7+,8+,9-;/m0./s1

Upstream product

• 64-17-5 ethanol 
• 14735-70-7 diexo-3-Aza-4-oxotricyclo<4.2.1.0^2,5>non-7-ene 
• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 92511-32-5 3-exo-aminobicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid 
• 53623-52-2 3-endo-Aminobicyclo<2.2.1>hept-5-ene-2-endo-carboxylic Acid 

Downstream Products

• 1446558-37-7 ethyl (1S,2R,3R,5S)-2-benzoylamino-3,5-divinylcyclopentanecarboxylate 
• 1446558-34-4 ethyl (1S,2S,3R,4R)-3-benzamidobicyclo[2.2.1]hept-5-ene-2-carboxylate 
• 104770-25-4 (1S,7R,8S)-3-Benzyl-5-oxa-3-aza-tricyclo[6.2.1.0^2,7]undec-9-ene 
• 105550-69-4 ((1S,2S,3R,4R)-3-Benzylamino-bicyclo[2.2.1]hept-5-en-2-yl)-methanol 
• 104770-12-9 (1R,2R,3S,4S)-3-Benzoylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 87768-87-4 2-(4-Chlorophenyl)-5,8-methano-r-4a,t-5,6,7,t-8,c-8a-hexahydro-4H-3,1-benzoxazine 
• 87768-88-5 2-(3-Chlorophenyl)-5,8-methano-r-4a,t-5,6,7,t-8,c-8a-hexahydro-4H-3,1-benzoxazine 
• 87768-86-3 2-(4-Tolyl)-5,8-methano-r-4a,t-5,6,7,t-8,c-8a-hexahydro-4H-3,1-benzoxazine 
• 95630-77-6 Ethyl 3-endo-Aminobicyclo<2.2.1>heptane-2-endo-carboxylate 
• 95630-80-1 2-exo-Methylamino-3-exo-hydroxymethylbicyclo<2.2.1>heptane 
• 78365-98-7 3-endo-Hydroxymethylbicyclo<2.2.1>heptyl-2-endo-amine 
• 95630-60-7 2-Phenyl-5,8-methano-r-4a,t-5,6,7,t-8,c-8a-hexahydro-4H-3,1-benzoxazine 
• 95630-75-4 Ethyl 3-endo-Aminobicyclo<2.2.1>heptane-2-endo-carboxylate Hydrochloride 

Relevant articles and documents

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Stereochemical Studies, 106. - Saturated Heterocycles, 110. - Synthesis of Methylene-bridged Partially Saturated Quinazolones

With imidates, esters (5-8) of di-endo (1 and 2) and di-exo (3 and 4) norbornane- and norbornene-β-amino acids yield methylene-bridged tetrahydro- (18 and 20) and hexahydro-4-quinazolinones (17 and 19); the reaction of the corresponding carboxamides (9-12

Stereochemical Studies. Part 103. Saturated Heterocycles. Part 107. Preparation of 3-Mono and 2,3-Di-substituted Pyrimidin-4(3H)-ones in Retro-Diels-Alder Reactions. The Correct 1,2-Disubstituted Structure of the Compounds previously described as 2,3-Disu

The orthofomate cyclization of carboxamides (4) obtained from 3-exo-aminobicyclohept-5-ene-2-exo-carboxylic acid (1) yielded intermediate 8,9,10-trinorbornene-fused pyrimidinones (5) and hence 3-substituted pyrimidin-4(3H)-ones (6) through the spli

Stereochemical Studies. 81 . Saturated Heterocycles. 69 . Preparation of Methylene-bridged 3,1-Benzoxazines, 3,1-Benzoxazin-2-ones and 3,1-Benzoxazine-2-thiones

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