106861-40-9

Basic information

• Product Name: No
• Synonyms: 1,2,12,13-Tetradehydrotuberostemonine;Bisdehydrotuberostemonine
• CAS NO: 106861-40-9
• Molecular Formula: C22H29NO4
• Molecular Weight: 371.46996
• Mol File: 106861-40-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: No(CAS DataBase Reference)
• NIST Chemistry Reference: No(106861-40-9)
• EPA Substance Registry System: No(106861-40-9)

Safety Data

• Hazardous Substances Data: 106861-40-9(Hazardous Substances Data)

Upstream product

• 6879-01-2 (-)-tuberostemonine 
• 171523-46-9 (2S,3aR,6S,7aR)-6-hydroxy-2,3,3a,6,7,7a-hexahydroindole-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester 
• 144534-49-6 (2S,3aR,7aR)-3a-hydroxy-6-oxo-2,3,3a,6,7,7a-hexahydroindole-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester 
• 171523-63-0 <2S-(2β,3aβ,7aβ)>-2,3,3a,6,7,7a-hexahydro-3a-benzoyloxy-6-oxo-1H-indole-1,2-dicarboxylic acid 1-benzyl 2-methyl ester 
• 171523-45-8 (2S,3aR,6S,7aR)-3a-(benzoyloxy)-6-hydroxy-2,3,3a,6,7,7a-hexahydroindole-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester 
• 486421-67-4 (2S,7aS,8R,10aR,10bS)-8-Hydroxy-1,2,4,5,6,7,7a,8,10a,10b-decahydro-azepino[3,2,1-hi]indole-2-carboxylic acid methyl ester 
• 486421-53-8 (2S,3₁S,7aS,10aR)-Methyl 8-oxo-1,2,3¹,4,5,6,7,7a,8,10a-decahydroazepino[3,2,1-hi]indole-2-carboxylate 
• 486421-48-1 6-(tert-butyldimethylsilanyloxy)-(2S,3,3aR,6S,7,7aR)-hexahydroindole-2-carboxylic acid methyl ester 
• 486421-65-2 1-(3-phenylallyl)-6-oxo-(2S,3,3aR,6,7,7aR)-hexahydro-1H-indole-2-carboxylic acid methyl ester 
• 486421-50-5 1-(3-phenylallyl)-6-hydroxy-(2S,3,3aR,6S,7,7aR)-hexahydro-1H-indole-2-carboxylic acid methyl ester 
• 486421-58-3 (5S)-(8-hydroxy-(1,2S,4,5,6,7,7aS,8S,10aR,10bS)-decahydroazepino[3,2,1-hi]indol-2-yl)-(3S)-methyldihydrofuran-2-one 
• 486421-51-6 7-allyl-1-(3-phenylallyl)-6-oxo-(2S,3,3aR,6,7,7aR)-hexahydro-1H-indole-2-carboxylic acid methyl ester 
• 486421-54-9 8-(tert-butyldimethylsilanyloxy)-(1,2S,4,7,7aS,8,10aR,10bS)-decahydroazepino[3,2,1-hi]indole-2-carboxylic acid methyl ester 
• 486421-55-0 8-(tert-butyldimethylsilanyloxy)-(1,2S,4,7,7aS,8,10aR,10bS)-decahydroazepino[3,2,1-hi]indole-2-carboxylic acid methoxymethyl amide 

Relevant articles and documents

Ir-Catalyzed Asymmetric Total Syntheses of Bisdehydrotuberostemonine D, Putative Bisdehydrotuberostemonine e and Structural Revision of the Latter

The first total syntheses of bisdehydrotuberostemonine D (8) and putative bisdehydrotuberostemonine E (9), two novel pyrrole Stemona alkaloids, along with the synthesis of bisdehydrotuberostemonine (3) have been completed in 12-13 steps. Our strategy harn

Asymmetric total syntheses of tuberostemonine, didehydrotuberostemonine, and 13-epituberostemonine

Detailed experimental approaches toward the pentacyclic Stemona alkaloids tuberostemonine and didehydrotuberostemonine and the close analogue 13-epituberostemonine are described. The syntheses originate with a hydroindolinone derivative that can be obtain