107713-58-6

Basic information

• Product Name: Benzene,1-(4-chlorophenoxy)-3-[[2-(4-ethoxyphenyl)-3,3,3-trifluoropropoxy]methyl]-
• Synonyms: Flufenprox; ICI-A 5682; PP 682
• CAS NO: 107713-58-6
• Molecular Formula: C₂₄H₂₂ClF₃O₃
• Molecular Weight: 450.8779
• Mol File: 107713-58-6.mol

Chemical Properties

• Boiling Point: 482.1°Cat760mmHg
• Flash Point: 245.4°C
• Density: 1.243g/cm³
• CAS DataBase Reference: Benzene,1-(4-chlorophenoxy)-3-[[2-(4-ethoxyphenyl)-3,3,3-trifluoropropoxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1-(4-chlorophenoxy)-3-[[2-(4-ethoxyphenyl)-3,3,3-trifluoropropoxy]methyl]-(107713-58-6)
• EPA Substance Registry System: Benzene,1-(4-chlorophenoxy)-3-[[2-(4-ethoxyphenyl)-3,3,3-trifluoropropoxy]methyl]-(107713-58-6)

Safety Data

• Hazardous Substances Data: 107713-58-6(Hazardous Substances Data)

Upstream product

• 40784-88-1 ethyl 4-ethoxyphenylacetate 
• 773135-75-4 ethyl 3-(4-chlorophenoxy)benzoate 
• 107714-92-1 ethyl 2-(4-ethoxyphenyl)-3,3,3-trifluoropropanoate 
• 72714-63-7 3-(4'-chlorophenoxy)-benzyl alcohol 
• 106-39-8 bromochlorobenzene 
• 7781-98-8 ethyl-3-hydroxybenzoate 
• 117467-36-4 (RS)-1,1,1-trifluoro-2-(4-ethoxyphenyl)propan-3-ol 

Relevant articles and documents

Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3: The important role of water as a promoter

Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3 reagent has been developed as a new method to prepare α-trifluoromethyl esters. This trifluoromethylation reaction represents the first example of fluoroalkylation of a non-fluorinated carbene precursor. Water plays an important role in promoting the reaction by activating the "CuCF3" species prepared from CuI/TMSCF3/CsF (1.0:1.1:1.1). The scope of this trifluoromethylation reaction is broad, and its efficiency is demonstrated in the synthesis of a variety of aryl-, benzyl-, and alkyl-substituted 3,3,3-trifluoropropanoates.

Insecticidal ethers

This invention relates to novel fluorinated ethers, useful as insecticides and acaricides, to processes and intermediates for their preparation, to insecticidal and acaricidal compositions thereof and to methods of combating and controlling insect and acarine pests therewith.

Process for intermediates for insecticidal compounds

The invention provides novel arylalkene compounds of formula I, a process for their preparation and their use as intermediates for insecticidal compounds, comprising, STR1 wherein W represents 1 to 4 substituents selected from halo, alkyl, alkoxy, haloalkyl, haloalkoxy and alkoxyalkyl, or W represents a bidentate alkylene or alkylenedioxy group linking adjacent carbon atoms, X represents fluoroalkyl, and Y is selected from chlorine, bromine and alkoxy; and a process for preparing said ethers. The compounds of formula I are prepared by reacting a ketone of formula: STR2 with a phosphonium salt of formula Hal - (Q) 3 P + -CH 2 -Y, where Hal - represents a halide ion and Q represents alkyl or aryl.