Asymmetric fluorinative dearomatization of tryptamine derivatives
An asymmetric fluorinative dearomatization reaction of tryptamine derivatives was developed by using a chiral anion phase transfer catalyst (PTC) system, and the preliminary results of the reaction mechanistic study were achieved. This method is characterized by a simple operation, facile introduction of a fluorine atom in a highly enantioselective manner and construction of two contiguous quaternary stereogenic centers.
Liang, Xiao-Wei,Liu, Chuan,Zhang, Wei,You, Shu-Li
supporting information
p. 5531 - 5534
(2017/07/07)
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