Utility of neodymium diiodide as a reductant in ketone coupling reactions
Matrix presented The viability of Ndl2 as a one-electron reducing agent in organic synthesis has been examined by studying coupling reactions between alkyl chlorides and ketones and aldehydes.
Evans, William J.,Workman, Penny S.,Allen, Nathan T.
Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.
Too, Pei Chui,Tnay, Ya Lin,Chiba, Shunsuke
supporting information
p. 1217 - 1225
(2013/07/26)
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