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3-AZEPAN-2-YLIDENE-PENTANE-2,4-DIONE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

108140-18-7

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108140-18-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 108140-18-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,8,1,4 and 0 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 108140-18:
(8*1)+(7*0)+(6*8)+(5*1)+(4*4)+(3*0)+(2*1)+(1*8)=87
87 % 10 = 7
So 108140-18-7 is a valid CAS Registry Number.

108140-18-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(azepan-2-ylidene)pentane-2,4-dione

1.2 Other means of identification

Product number -
Other names 3-AZEPAN-2-YLIDENE-PENTANE-2,4-DIONE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108140-18-7 SDS

108140-18-7Relevant articles and documents

Synthesis of [1,2-A]-fused tricyclic dihydroquinolines by palladiumcatalyzed intramolecular C-N cross-coupling of polarized heterocyclic enamines

Bro?, B?etislav,R??i?ková, Zdeňka,?im?nek, Petr

, p. 118 - 141 (2016/10/22)

A simple methodology for [1,2-A]-fused tricyclic dihydroquinolines is established. The key ste of the methodology is an intramolecular Buchwald-Hartwig amination reaction of suitabl halogenated (both bromo and chloro) cyclic enaminoketones, enaminoesters and enaminonitrile with various ring size (from five-to seven-membered). Optimal reaction conditions (palladiu source, base, ligand) depend on the ring size of the starting enamine, giving 65-98% yield of th tricyclic product. A treatment of the products with perchloric acid gives respective quinoliniu perchlorates.

New triazaborine chromophores: Their synthesis via oxazaborines and electrochemical and DFT study of their fundamental properties

Josefík, Franti?ek,Mikysek, Tomá?,Svobodová, Markéta,?im?nek, Petr,Kvapilová, Hana,Ludvík, Ji?í

, p. 4931 - 4939 (2015/04/27)

Eight new and stable triazaborine chromophores featuring various substituents as donor and acceptor moieties were prepared and investigated. An interpretation of the measured electrochemical data (CV, RDV, and dc polarography) and UV - vis spectra and quantum chemical calculations are presented. In the homologous series the first reduction proceeds as a one-electron reversible process localized at the - N=C - C=N - part of the central heterocycle being in conjugation with the attached carbonyl. The first oxidation of triazaborines proceeds as a two-electron irreversible process, most probably of the ECE type, localized at the negatively charged boron atom and surrounding unsaturated structures, including the substituted phenyl ring. For a better understanding of the relationship between the structure and redox properties, the LFER approach was applied for the first oxidation as well as reduction potential using the Hammett σ (para) substituent constants. The energies of the longest-wavelength absorption bands taken from UV-vis spectra were compared with the experimentally found differences Eox - Ered and with calculated HOMO-LUMO gaps, and no systematic influence of substitution was found. The calculated optimized structures and displacement of the frontier orbitals confirmed the interpretations presented above. (Figure Presented)

A new bicyclic oxazaborines with a bridged nitrogen atom, their thermic rearrangement and fluorescence properties

Josefík, Franti?ek,Svobodová, Markéta,Bertolasi, Valerio,?im?nek, Petr,MacHá?ek, Vladimír,Almonasy, Numan,?erno?ková, Eva

supporting information; experimental part, p. 75 - 81 (2012/02/16)

Cyclic β-enaminones bearing secondary amino group react with 4-substituted benzenediazonium tetraphenylborates in dichloromethane to form substituted bicyclic [1,3,2λ4]oxazaborines The oxazaborines rearrange, on heating to 200 °C in the absence of solvent or in DMF or DMSO, to isomeric 2H-[1,2,4,3λ4]triazaborines. Previously prepared [1,3,2λ4]oxazaborines derived from acyclic β-enaminones bearing secondary amino group either did not undergo the rearrangement or with a lot of difficulties and with negligible yield. The fluorescence behaviour of the prepared triazaborines was observed. These compounds fluoresce in 2-methyltetrahydrofurane and in solid state under low temperatures.

Synthesis of acetyl-substituted heterocyclic enamines and their reaction with diethyl azodicarboxylate

Cheng,Zhao,Wang,Wang,Huang

, p. 1339 - 1351 (2007/10/02)

Acetyl-substituted heterocyclic enamines 4 were synthesized from lactim ethers 2 and acetylacetone through condensation and deacetylation reactions, and they, along with the ester-substituted heterocyclic enamines 6, reacted with diethyl azodicarboxylate to afford C-adducts 7 and 8 in excellent yields.

Acylation des β-enaminoesters: regio et stereoformation des β-enaminoesters N- ou C-acyles

Brunerie, Pascal,Celerier, Jean-Pierre,Petit, Huguette,Lhommet, Gerard

, p. 1183 - 1188 (2007/10/02)

The reaction of acyl chlorides with cyclic five-membered β-enaminoesters gave exclusively N-acylated products while reaction of acyl chlorides with cyclic seven-membered β-enaminoesters gave only C-acylated products.In the case of cyclic six-membered β-en

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