- Synthesis of Chromones from 1,1-Diacylcyclopropanes: Toward the Synthesis of Bromophycoic Acid e
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A tandem deprotection-cyclization reaction of 1,1-diacylcyclopropanes is described which allows rapid access to structurally diverse 2,3-disubstituted chromones in good yields, and with straightforward purification. The utility of this reaction is showcas
- Smith, Robert J.,Nhu, Duong,Clark, Mitchell R.,Gai, Sinan,Lucas, Nigel T.,Hawkins, Bill C.
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- An easy construction of 8,12-dioxa-13- azatricyclo[8.3.1.02.7]tetradeca-2(7),3,5,13-tetraen-14-ones
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8,12-Dioxa-13-azatricyclo[8.3.1.02.7]tetradeca-2(7),3,5,13-tetraen- 14-ones are obtained in moderate yield by treatment of oximes of o- allyloxyacetophenones with [hydroxy(tosyloxy)iodo]benzene in acetonitrile.
- De, Surya K.,Mallik, Asok K.
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- Visible-Light-Induced External Radical-Triggered Annulation to Access CF2-Containing Benzoxepine Derivatives
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A facile and diversified synthesis of functionalized CF2-containing benzoxepine derivatives via photoredox catalysis was achieved in this work. This novel protocol features broad substrate scope, mild reaction conditions, operational simplicity, easy scale-up, and versatile derivatization, which would facilitate its practical and broad applications in the construction of valuable and synthetically challenging heterocycles.
- Xiang, Haoyue,Zhao, Qing-Lan,Xia, Peng-Ju,Xiao, Jun-An,Ye, Zhi-Peng,Xie, Xiong,Sheng, Huan,Chen, Xiao-Qing,Yang, Hua
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supporting information
p. 1363 - 1366
(2018/03/09)
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- Synthesis of novel 8-[2-hydroxy-3-(alkylamino)propyl]-4-methoxy coumarins
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A series of new 8-[-2-hydroxy-3(alkylamino) propyl]-4-methoxy coumarins 7a-e, 8a-e have been synthesized from 3-allyl-2-hydroxy acetophenones 3a-e via key intermediate 8-(2-oxerane methyl)-4-methoxy coumarins 6a-e by regioselective opening of epoxide with
- Dalal, Shailendara,Rao, Y. Jayaprakash,Krupadanam, G. L. David
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p. 805 - 810
(2015/06/30)
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- Use of Pyrylium Synthons in the Synthesis of Hemispherands with Modified Cavities. X-ray Structures of the 21-Hemispherand and a Pyrido Hemispherand
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The effect of variation of the rigid part of the parent Cram hemispherand 1a on the preorganization of the macrocyclic cavity has been studied.Four novel 18-membered hemispherands (3,4a-c)have been synthesized via a novel multistep route using 2,6-di- and
- Dijkstra, Pieter J.,Hertog, Herman J. den,Steen, Bart J. van,Zijlstra, Sietze,Skowronska-Ptasinska, Maria
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p. 2433 - 2442
(2007/10/02)
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