- Synthesis od Some Substituted Adamantanetriones
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Acryloyl and crotonoyl chlorides react with the morpholine enamine of 4-ethoxy-carbonyl-4-phenylcyclohexanone to give 1-phenyladamantane-2,4,6-trione and 10a-methyl-1-phenyladamantane-2,4,6-trione, respectively.The structures of the compounds were determined by their 1H and 13C nmr, 1H-1H nmr COSY, 1H-13C nmr COSY and mass spectral data.The course of the reactions leading to the formation of the adamantanetriones and the stereochemistry at the chiral centre, 10-C, are also discussed.
- Ahmed, M. Giasuddin,Moeiz, S. M. Iqbal,Ahmed, S. Asghari,Hena, M. Abu,Tsuda, Yoshisuke,Sampson, Paul
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p. 1082 - 1095
(2007/10/03)
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