Anomalously Coupled Nucleosides, III. - Coupling of Unprotected 2-Deoxy-D-ribose at C-3 with N6-Acyladenines as a New Route to Isomers of Adenosine
Anomalous coupling at C-3 of unprotected 2-deoxy-D-ribose (2) with N6-acyladenosines 1 was performed using P4O10/H2O/Bu3N in chloroform as the coupling reagent.The 3-(9-adenyl)-2,3-dideoxy-D-threo-pentopyranoses 3 formed were deprotected with ammonia in methanol to give the anomalously coupled isomer 5 of adenosine.
Motawia, Mohammed S.,Andreassen, Erik S.,Pedersen, Erik B.,Jacobsen, Jens Peter
p. 787 - 791
(2007/10/02)
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