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111002-63-2

iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br} is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 111002-63-2 Structure

  • Basic information

    1. Product Name: iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br}
    2. Synonyms: iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br}
    3. CAS NO:111002-63-2
    4. Molecular Formula:
    5. Molecular Weight: 821.558
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 111002-63-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br}(CAS DataBase Reference)
    10. NIST Chemistry Reference: iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br}(111002-63-2)
    11. EPA Substance Registry System: iron(η2-CS2Et)(carbonyl)2((phenyl)3phosphine)2{Br}(111002-63-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 111002-63-2(Hazardous Substances Data)

111002-63-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 111002-63-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,1,0,0 and 2 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 111002-63:
(8*1)+(7*1)+(6*1)+(5*0)+(4*0)+(3*2)+(2*6)+(1*3)=42
42 % 10 = 2
So 111002-63-2 is a valid CAS Registry Number.

111002-63-2Relevant articles and documents

Electron transfer from borohydride and selective reductions of iron cations. Synthesis of tetrathiooxalate iron derivatives

Touchard, Daniel,Fillaut, Jean-Luc,Khasnis, Dilip V.,Dixneuf, Pierre H.,Mealli, Carlo,Masi, Dante,Toupet, Lo?c

, p. 67 - 75 (2008/10/08)

Cations of the type Fe(η2-CS2R)(CO)2(L)2+ (L = PPh3; R = Me (2a), Et (2b), CH2C(Me)=CH2 (2c)) react with NaBH4 to afford, via electron transfer, C-C coupling products (RS)2C2S2Fe2(CO)4(L) 2 (3a-c). Complexes 2 containing an acylalkyl group, R, also give complexes 3d,e, but only on reduction with activated magnesium. Reduction of cations 2a-c with sodium amalgam leads first to 3a-c and then to the (RS)2C2S2Fe(CO)2(L) complexes (4). Complexes 4a-c are also obtained on treatment of 3a-c with Lewis acids in the presence of air. Cation 2h (L = P(OMe)3, R = Me) is less easily reduced (Ec = -0.81 V vs SCE) than 2a (L = PPh3; Ec = -0.74 V vs SCE) and, when treated with NaBH4, undergoes electron transfer and hydride addition: complex 6, analogous to 3, and Fe(η2-HCS2Me)(CO)2L2 (5) are thus formed. Reaction of 2h with Na/Hg affords by contrast small amounts of FeCS(CO)2L2 (8) and (R2S)2C2S2Fe(CO)L2 (9). The X-ray diffraction structures of 3a and 4a have been determined. 3a: space group P1, Z = 2, a = 9.669 (2) A?, b = 13.477 (3) A?, c = 17.323 (3) A?, α = 101.1 (2)°, β = 91.5 (2)°, γ = 110.3 (2)°, V = 2048 A?3, R = 0.058 for 3802 reflections having I > σ(I). 4a: space group P21/a, Z = 4, a = 24.144 (6) A?, b = 10.017 (2) A?, c = 10.745 (2) A?, α = 97.38 (2)°, V = 2577 A?3, R = 0.084 for 2440 reflections having I > 3σ(I).

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