ASYMMETRIC NITROGEN. COMMUNICATION 50. NATURE OF THE EFFECT OF SUBSTITUENTS ATTACHED TO THE C ATOM ON THE REACTIVITIES OF DIAZIRIDINES; SYNTHESIS AND PHOTOELECTRONIC SPECTRA OF FUNCTIONALLY SUBSTITUTED 1,n-DIAZABICYCLOALKANES
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Shustov, G. V.,Denisenko, S. N.,Kostyanovskii, R. G.
p. 1662 - 1667
(2007/10/02)
1,2-Acyl Migration to an Electron-deficient Nitrogen Atom: a New Rearrangement of Diaziridines without Ring Opening
5-Acyl-1,6-diazabicyclohexane (1) on treatment with t-butyl hypochlorite affords the corresponding N-chloro-derivative (2) which rearranges easily into 6-acyl-5-chloro-1,6-diazabicyclohexane (3) with a 1,2-shift of the acyl group.
Denisenko, Sergei N.,Shustov, Gennady V.,Kostyanovsky, Remir G.
p. 1275 - 1276
(2007/10/02)
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