112426-02-5

Basic information

• Product Name: LITHIUM 2-THIENYLCYANOCUPRATE 0.25M
• Synonyms: LITHIUM 2-THIENYLCYANOCUPRATE 0.25M;LITHIUM 2-THIENYLCYANOCUPRATE, 0.25M SOL UTION IN TETRAHYDROFURAN;lithium 2-thienylcyanocuprate solution;Lithium 2-thienylcyanocuprate solution 0.25 in THF;LithiuM 2-thienylcyanocuprate, 0.25M solution in THF, AcroSeal;LithiuM 2-thienylcyanocuprate solution,0.25 M in THF
• CAS NO: 112426-02-5
• Molecular Formula: C₅H₃CuNS*Li
• Molecular Weight: 179.64
• Product Categories: Organocopper;Organometallic Reagents;Others;Chemical Synthesis;Organometallic Reagents
• Mol File: 112426-02-5.mol

Chemical Properties

• Flash Point: 1 °F
• Appearance: /
• Density: 0.895 g/mL at 25 °C
• CAS DataBase Reference: LITHIUM 2-THIENYLCYANOCUPRATE 0.25M(CAS DataBase Reference)
• NIST Chemistry Reference: LITHIUM 2-THIENYLCYANOCUPRATE 0.25M(112426-02-5)
• EPA Substance Registry System: LITHIUM 2-THIENYLCYANOCUPRATE 0.25M(112426-02-5)

Safety Data

• Hazard Codes: F,T,Xn
• Statements: 11-19-23/24/25-36/37/38-40-36/37
• Safety Statements: 16-23-26-36/37/39-45-36/37
• RIDADR: UN 1992 3/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 112426-02-5(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 112426-02-5 differently. You can refer to the following data:
1. LITHIUM 2-THIENYLCYANOCUPRATE 0.25M is useful reagent for the preparation of higher-order cuprates.1
2. Useful reagent for the preparation of higher-order cuprates.

General Description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Upstream product

• 188290-36-0 thiophene 
• 544-92-3 copper(I) cyanide 
• 109-72-8 n-butyllithium 

Downstream Products

• 146656-03-3 2-Phenyl-2-thiophen-2-yl-ethanol 
• 146656-06-6 2-(5,6-Dihydro-[1,4]dioxin-2-yl)-2-phenyl-ethanol 
• 629-59-4 tetradecane 
• 170211-85-5 (R)-6-tert-Butyl-2-hydroxy-cyclohex-1-enecarboxylic acid (1R,2S,3R,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 170116-94-6 (S)-6-tert-Butyl-2-hydroxy-cyclohex-1-enecarboxylic acid (1R,2R,3S,4S)-3-[benzenesulfonyl-(3,5-dimethyl-phenyl)-amino]-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 57242-85-0 3-n-octylcyclohexanone 

Relevant articles and documents

Generation of Aryllithium Reagents from N -Arylpyrroles Using Lithium

Treatment of 1-aryl-2,5-diphenylpyrroles with lithium powder in tetrahydrofuran at 0 °C results in the generation of the corresponding aryllithium reagents through reductive C-N bond cleavage.

12-ARYL PROSTAGLANDIN ANALOGS

Compounds comprising the formula (I) are disclosed, wherein Y, A, X, R, D, and n are as described. A compound comprising a prostaglandin EP2 selective agonist wherein the ω-chain comprises a substituted phenyl, wherein at least one substituent

Process for preparing prostaglandins

A process for preparing prostaglandin derivatives by reacting a trans bis-tin ethylene with an organo metal compound then with a compound selected from an epoxide, aldehyde, or ketone, then, without isolation and in the same reaction vessel, reacting with an organo lithium compound, a cuprate complex and a cyclopentenone to produce a prostaglandin intermediate having an unprotected hydroxyl group on the omega side chain.