544-92-3Relevant articles and documents
METHOD FOR PREPARING LAMOTRIGINE AND ITS INTERMEDIATE 2,3-DICHLOROBENZOYL CHLORIDE
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Page/Page column 14, (2010/11/29)
The invention relates to an improved method for preparing 3,5-diamino-6-(2,3-dichlorophenyl)-1,2,4-triazine, also commonly known as lamotrigine. The present invention also relates to a method for preparing the intermediate 2,3-dichlorobenzoyl chloride, which comprises the synthesis by photochlorination of 2,3-dichlorobenzotrichloride followed by hydrolysis thereof. Said 2,3-dichlorobenzoyl chloride intermediate is useful for preparing lamotrigine.
Electrochemistry of cyanocopper thiomolybdates and thiotungstates: Redox-based interconversion of species
Kony, Michael,Bond, Alan M.,Wedd, Anthony G.
, p. 4521 - 4525 (2008/10/08)
[MoS4]2- and its 1:1 and 1:2 CuCN adducts [(CN)CuS2MoS2]2- and [(CN)CuS2MoS2Cu(CN)]2- each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s-1). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties.