116-50-7Relevant articles and documents
Synthesis method of benzenesulfonate derivative
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Paragraph 0017-0029, (2021/06/13)
The invention discloses a synthesis method of a benzenesulfonate derivative. A raw material described in the specification reacts with ethylene glycol to generate a compound described in the specification, wherein R1 is selected from alkyl, H or F. The sy
Synthetic method of benzenesulfonate derivative
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Paragraph 0032; 0033; 0035, (2018/05/03)
The invention relates to a synthetic method of a benzenesulfonate derivative and belongs to the technical field of synthesis of compounds. A compound (described in the specification) is taken as raw materials, and reaction is carried out with ethylene glycol or R2-OH to generate a compound (described in the specification), wherein R1 is selected from alkyl, H or F, and R2 is selected from allyl, propargyl or benzene. The synthetic method provided by the invention comprises the following concrete operations: adding ethylene glycol or R2-OH and dichloromethane into a reactor, adding organic alkali while stirring, then cooling to the temperature below 15 DEG C, starting to dropwise add a substance (described in the specification), after the substance is dropwise added, returning to room temperature and further stirring for 0.5-1 hour, then heating and carrying out reflux reaction for 1-2 hours, after the reflux reaction is complete, carrying out ice thawing treatment, layering, drying, and concentrating, so that the benzenesulfonate derivative product is obtained. The synthetic method provided by the invention is simple, reaction process is mild and stable, yield is high, and the obtained product is high in purity.
Technique for compounding glycol dibenzenesulfonate by nanometer solid alkali catalyst
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Paragraph 0031-0037; 0052; 0073, (2017/08/28)
The invention discloses a technique for compounding glycol dibenzenesulfonate by nanometer solid alkali catalyst. The glycol dibenzenesulfonate is prepared by taking glycol, pyridine, benzene sulfonyl chloride, and self-made caesium-modified nanometer Ti/
Technology for synthesizing glycol dibenzenesulfonate from nano-solid alkali catalyst
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Paragraph 0030-0037; 0052; 0056, (2017/08/28)
The invention discloses a technology for synthesizing glycol dibenzenesulfonate from a nano-solid alkali catalyst. Glycol dibenzenesulfonate is prepared from raw materials including glycol, pyridine, benzene sulfonyl chloride, the home-made caesium modified nano-scale Ti/Al composite solid alkali catalyst and the like through operating means including ice-water bath, reduced-pressure distillation, magnetic stirring and the like.
Disulfonic acid ester compound for preparing olefin polymerization catalyst
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Paragraph 0062; 0063; 0064, (2016/12/16)
The invention relates to a disulfonic acid ester compound for preparing an olefin polymerization catalyst. The disulfonic acid ester compound is shown in the general formula (I), wherein A and B are carbon or hetero atoms selected from nitrogen, oxygen, s
Radiosyntheses and reactivities of novel [18F]2-fluoroethyl arylsulfonates
Musachio, John L.,Shah, Jay,Pike, Victor W.
, p. 735 - 747 (2007/10/03)
[18F]2-Fluoroethyl tosylate ([18F]FEOX, X = Ts) is widely used for labeling radiotracers for positron emission tomography (PET). Little work has been reported on syntheses of other [18F]2- fluoroethyl arylsulfonates ([sup