Access to cyclopropyl cations via carbene fragmentation
Photolysis of cyclopropyloxychlorodiazirines affords cyclopropyloxychlorocarbenes whose fragmentations provide access to ion pairs, which feature cyclopropyl cations.
Moss, Robert A.,Chu, Gaosheng
p. 3321 - 3326
(2007/10/03)
FREE RADICAL CHLORINATION AND ONE-ELECTRON OXIDATION OF ARYLCYCLOPROPANES. DESIGNER PROBES FOR CYTOCHROME P-450 HYDROXYLATION MECHANISMS
Arylcyclopropyl radicals can be formed under mild conditions (phase-transfer-catalyzed chlorination) and give rise to cyclopropyl products; in contrast one-electron oxidation of arylcyclopropanes by Mn(OAc)3 leads to fragmentation of the cyclopropane ring and the formation of acyclic products.
Riley, Pamela,Hanzlik, Robert P.
p. 3015 - 3018
(2007/10/02)
Reinvestigation of the Metalation of Phenylcyclopropane: Does the Phenylcyclopropyl Anion Undergo Ring-Opening?
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Ogle, Craig A.,Riley, Patrick A.,Dorchak, Joseph J.,Hubbard, John L.
p. 4409 - 4412
(2007/10/02)
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