117470-88-9

Basic information

• Product Name: DIISOPROPYL (4R,5R)-1,3,2-DIOXATHIOLANE- 4,5-DICA.LA.DIOXIDE
• Synonyms: DIISOPROPYL (4R,5R)-1,3,2-DIOXATHIOLANE- 4,5-DICA.LA.DIOXIDE;diisopropyl 1,3,2-dioxathiolane-4,5-dicarboxylate dioxide;(-)-Diisopropyl 2,3-O-sulfonyl-L-tartrate, Diisopropyl L-tartrate cycl-sulfate;Diisopropyl (4R,5R)-1,3,2-dioxathiolane-4,5-dicarboxylate 2,2-dioxide;(?)-Diisopropyl 2,3-O-sulfonyl-L-tartrate;Diisopropyl L-tartrate cycl-sulfate
• CAS NO: 117470-88-9
• Molecular Formula: C10H16O8S
• Molecular Weight: 296.29
• Mol File: 117470-88-9.mol

Chemical Properties

• Flash Point: 110 °C
• Appearance: /
• Refractive Index: n20/D 1.434
• Storage Temp.: 2-8°C
• CAS DataBase Reference: DIISOPROPYL (4R,5R)-1,3,2-DIOXATHIOLANE- 4,5-DICA.LA.DIOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIISOPROPYL (4R,5R)-1,3,2-DIOXATHIOLANE- 4,5-DICA.LA.DIOXIDE(117470-88-9)
• EPA Substance Registry System: DIISOPROPYL (4R,5R)-1,3,2-DIOXATHIOLANE- 4,5-DICA.LA.DIOXIDE(117470-88-9)

Safety Data

• Safety Statements: 23-24/25
• Hazardous Substances Data: 117470-88-9(Hazardous Substances Data)

Upstream product

• 62961-64-2 D-(-)-diisopropyl tartrate 
• 136029-38-4 (4R,5R)-2-Oxo-2λ⁴-[1,3,2]dioxathiolane-4,5-dicarboxylic acid diisopropyl ester 
• 2217-15-4 L-(+)-diisopropyl tartrate 

Relevant articles and documents

Efficient synthesis of chiral α,β-epoxyesters via a cyclic sulfate intermediate

An efficient synthesis of chiral α,β-epoxyester 1 from chiral 2,3- dihydroxyester 2 has been developed. Ester 2 is converted to the corresponding cyclic surfate 3, which is opened with either LiBr in THF or Bu4NBr in acetone at rt to furnish 2-bromo-3-hydroxyester 4. Treatment of 4 with K2CO3 in methanol at low temperature gives α,β-epoxyester 1 in excellent overall yield and in the same ee as in the starting diol.