- Reactive dye having both monochlorotriazinyl and vinylsulfone type reactive groups
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A novel reactive monoazo dye, capable of giving cellulose fiber materials a deep orange to scarlet color and superior in build-up and chlorine fastness properties, represented by a free acid of the formula, STR1 wherein R1 is hydrogen, methyl or ethyl; R2 is an alkyl having 1 to 4 carbons that is either unsubstituted or substituted with hydroxy, cyano, alkoxy, halogen, carboxy, alkoxycarbonyl or sulfonic acid; Z is hydrogen or sulfonic acid; A is phenylene and is either unsubstituted or substituted with 1 or 2 substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfonic acid, or natphthylene that is either unsubstituted or substituted with sulfonic acid; X is --SO2 CH=CH2 or --SO2 CH2 CH2 Y in which Y is a group that is splittable by alkalis; and m is an integer of 1 to 3.
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- Fiber reactive monoazo compounds having two vinylsulfone type fiber reactive groups in the molecule
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A monoazo compound of the following formula in a free acid form, STR1 wherein A1 and A2 are phenylene or naphthylene, Z1 and Z2 are --SO2 CH=CH2 or --SO2 CH2 CH2 Y in which Y is a splittable group, R1 and R2 are hydrogen or alkyl, and D is sulfophenyl or sulfonaphthyl, provided that --A1 --Z1 and --A2 --Z2 are different from each other when D is sulfophenyl and both R1 and R2 are hydrogen, which is useful for dyeing or printing fiber materials to give dyed products of high fastness properties with extremely high color depth.
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- Bisazo brown reactive dye
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A brown reactive dye represented by a free acid of the formula, STR1 wherein R is a hydrogen atom or a C1 to C4 alkyl group, X is --SO2 CH2 CH2 Cl, --SO2 CH=CH2, --SO2 CH2 CH2 OSO3 H or --SO2 CH2 CH2 OPO3 H2, rings A, B and C are each a benzene or naphthalene ring which may have other substituent, m is 0 to 3 and n is 0 to 1. This dye is suitable for dyeing cellulose fibers brown to afford dyeings superior in fastnesses, acid stability, build-up property and level dyeing property.
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- Fiber-reactive disazo brown dye having vinylsulfone-type reactive group
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A compound, or a salt thereof, represented by the following formula, STR1 wherein A is a substituted or unsubstituted phenylene or naphthylene group, B is STR2 in which R3 is a hydrogen atom or a lower alkyl, lower alkoxy, acylamino or ureido group, and R4 is a hydrogen atom or a lower alkyl or lower alkoxy group, R1 and R3 are independently a hydrogen atom or a substituted or unsubstituted lower alkyl group, X is a substituted or unsubstituted amino, lower alkoxy, substituted phenoxy or sulfo group, Y is --SO2 CH=CH2 or --SO2 CH2 CH2 Z, in which Z is a group capable of being split by the action of an alkali, and m is 2 or 3, which is useful for dyeing hydroxyl group- or amide group-containing fiber materials to give dyed products of a brown color having excellent fastness properties with good build-up property.
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- Reactive disazo dyestuffs containing triazines
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Reactive azo dyestuffs which, in the form of free acid, are represented by the following formula: STR1 (wherein R is hydrogen or methyl) are characterized by exhibiting the following properties: high fixation efficiency, excellent wash-off, high build-up and excellent wet fastness. Such dyestuffs give dyeings excellent in light fastness, chlorine fastness and color yield.
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- Process for monoacylating water-soluble organic amino compounds
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A process for the monoacylation of water-soluble organic amino compounds with 2,4,6-trifluoro-s-triazine, which comprises introducing all reactants simultaneously and continuously in the amounts necessary for the required throughput into the reaction space and removing the resultant reaction products continuously therefrom.
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- Azo dyestuffs
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Azo dyestuffs, which in the acid form, are represented by the formula: wherein A is an aromatic radical, M is a 1,4-benzene radical which may be substituted, E is the residue of a coupling component which is free from azo groups, At least one of A and M containing a phosphonic acid group, and the metal complexes of those having a metallisable group are reactive dyes suitable for use in the process of German OLS No. 2324809.
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- Process for producing amino G acid and amino J acid from tobias acid
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A novel process for producing 2-amino-6,8-naphthalenedisulfonic acid (Amino G Acid) and 2-amino-5,7-naphthalenedisulfonic acid (Amino J Acid) which comprises heating 2-amino-1-naphthalenesulfonic acid (Tobias Acid) in 100% sulfuric acid, sulfonating the heated mixture with sulfur trioxide at a temperature in the range of 90°C. to 150°C. and hydrolyzing the sulfonation product.
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