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B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate is a complex chemical compound derived from glucose, featuring multiple functional groups such as glucopyranose, anhydride, azide, and acetate. Its unique structure and functional groups make it a valuable target for research in organic chemistry and biochemistry.

119005-80-0

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119005-80-0 Usage

Uses

Used in Organic Chemistry Research:
B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate is used as a key intermediate in the synthesis of various glycosidic compounds, which are essential for studying carbohydrate chemistry and its role in biological systems.
Used in Biochemistry Research:
B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate is utilized in biochemistry research to explore its interactions with biological molecules and its potential applications in understanding carbohydrate-based biological processes.
Used in Drug Development:
B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate holds promise in the development of new drugs or materials due to its unique structure and functional groups, which can be further modified or used as a starting point for creating novel therapeutic agents.
Used in Material Science:
B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate's versatile functional groups and complex structure make it a candidate for the development of new materials with specific properties, such as in the fields of nanotechnology or polymer science.

Check Digit Verification of cas no

The CAS Registry Mumber 119005-80-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,9,0,0 and 5 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 119005-80:
(8*1)+(7*1)+(6*9)+(5*0)+(4*0)+(3*5)+(2*8)+(1*0)=100
100 % 10 = 0
So 119005-80-0 is a valid CAS Registry Number.

119005-80-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name B-D-Glucopyranose,1,6-anhydro-2-azido-2-deoxy-,3,4-diacetate

1.2 Other means of identification

Product number -
Other names 3,4-di-n-octyloxyacetophenone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:119005-80-0 SDS

119005-80-0Relevant articles and documents

The oxolane ring opening of some muramic acid derivatives under acidic conditions

Samaszko-Fiertek, Justyna,Dmochowska, Barbara,?lusarz, Rafa?,Madaj, Janusz

, p. 693 - 697 (2018/07/13)

Synthesis of 1,6-anhydro sugars is well known in literature. The dioxolane ring exhibits at least two types of properties. It can be used as a protecting group and reaction site. This work discusses the cleavage of the 1,6-anhydro ring of muramic acid derivatives. To induce the opening of the dioxolane ring in 1,6-anhydro-D-glucose derivatives three types of reagents were used (TFA/Ac2O, Sc(OTf)3/Ac2O, H2SO4/Ac2O). This method is commonly used in sugar chemistry for opening 1,6-anhydro ring. This process led to the preparation of compounds with very good yields (80%, even 98%). In the first attempt the mixture of TFA/Ac2O (1:9) was used. Besides the main product 4, the 3,4-di-Oacetyl- 1,6-anhydro-2-azide-2-deoxy-β-D-glucopyranose was observed as a side product. Main product 4 was obtained as the mixture of α and β (2:1) anomers. Better stereoselectivity was obtained using Sc(OTf)3. In this case, the main product was received with β configuration. The best yield (65%) was obtained using a mixture of H. In this case, the main product was received with β configuration. The best yield (65%) was obtained using a mixture of H2SO4 and Ac2O and mixture of two anomers of N-acetyl-1,4,6-tri-Oacetyl- 2-deoxy-D-muramic acid ethyl ester was isolated (α and β, 1:4). Depending on which method was used to open dioxolane ring of 1,6-anhydroMur derivative we were able to control the stereochemistry of the reaction and to obtain pure α anomer or mostly β anomer.

Synthesis of a heparan sulfate mimetic disaccharide with a conformationally locked residue from a common intermediate

Fairweather, Jon K.,Karoli, Tomislav,Liu, Ligong,Bytheway, Ian,Ferro, Vito

experimental part, p. 2394 - 2398 (2010/01/03)

A simple mimetic of a heparan sulfate disaccharide sequence that binds to the growth factors FGF-1 and FGF-2 was synthesized by coupling a 2-azido-2-deoxy-d-glucopyranosyl trichloroacetimidate donor with a 1,6-anhydro-2-azido-2-deoxy-β-d-glucopyranose acceptor. Both the donor and acceptor were obtained from a common intermediate readily obtained from d-glucal. Molecular docking calculations showed that the predicted locations of the disaccharide sulfo groups in the binding site of FGF-1 and FGF-2 are similar to the positions observed for co-crystallized heparin-derived oligosaccharides obtained from published crystal structures.

Facile Preparation of 3,4-Di-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose and Some Derivatives Thereof: Useful Precursors for Oligosaccharide Synthesis

Dasgupta, Falguni,Garegg, Per J.

, p. 626 - 628 (2007/10/02)

A facile, virtually one-pot synthesis of the title compound and also some of its derivatives is based on regioselective 2-substitutions of 1,6-anhydro-β-D-mannopyranose using stannylidene activation.The compounds thus prepared are useful precursors in the synthesis of glycoprotein-type oligosaccharides.

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