- Aryl 1,5-dithia-2,4,6,8-tetrazocines. A synthetic, electrochemical, and structural investigation
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New preparative routes to the title compounds are reported in which the yields are substantially improved over previous methods.In one method, reaction of O2 with a mixture of XC6H4CN2S2(+)*Cl(-) and Ph3Sb leads to the products in 40-60percent yield.In an
- Boere, Rene T.,Moock, Klaus H.,Derrick, Sean,Hoogerdijk, William,Preuss, Kathryn,et al.
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p. 473 - 486
(2007/10/02)
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- HETEROCYCLES FROM SILYLATED AMIDINES. PREPARATION OF 1,3,2,4,6-DITHIATRIAZINES; PREPARATION AND E.S.R. CHARACTERIZATION OF NEW 1,2,3,5-DITHIA- AND DISELENADIAZOLYL RADICALS; THE CONVERSION OF DITHIADIAZOLYLS TO 1,5,2,4,6,8-DITHIATETRAZOCINES BY REACTION W
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The synthesis of 3- and 4-substituted aryl dithiatriazines, 2, (X = 4-CH3, 4-Cl, 3-CF3, 4-CF3, 4-CH3O, 4-C6H5); dithiadiazolyl radicals 4-X-C6H4CN2S2 (X = CH3, CH3O, Cl, NO2, and CF3) and their dimers in the solid state and four new diselenadi
- Boere, Rene T.,Larsen, Karen,Fait, James,Yip, Judy,Moock, Klaus H.
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p. 143 - 146
(2007/10/02)
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- Preparation of Dithiatetrazocines and Secondary Reactions
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Li (1) or PhCN2(SiMe3)3 (3) react with SCl2 to give in good yields the dithiatetrazocine PhC(NSN)2CPh (2).By analogy, p-MeC6H4C(NSN)2CC6H4Me-p (7), p-NO2C6H4C(NSN)2CC6H4NO2-p (8), and p-CF3C6H4C(NSN)2CC6H4CF3-p (9) are obtained from the rea
- Scholz, Uwe,Roesky, Herbert W.,Schimkowiak, Juergen,Noltemeyer, Mathias
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p. 1067 - 1070
(2007/10/02)
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