12060-00-3

Basic information

• Product Name: LEAD TITANIUM OXIDE
• Synonyms: LEAD TITANATE, POWDER, ;LEAD TITANATE, 99.9%;Lead(II)titanate,99.5%;Lead titanium oxide (PbTiO3);Lead titanium oxide, 99.9% (metals basis);Lead titanium oxide, 99.5%;Lead titanium oxide, polymeric precursor, oxide >30 wt%;Lead titanate(IV)
• CAS NO: 12060-00-3
• Molecular Formula: O3PbTi
• Molecular Weight: 303.07
• EINECS: 235-038-9
• Product Categories: Inorganics;Ceramics;Metal and Ceramic Science;Titanates;metal titanate
• Mol File: 12060-00-3.mol

Chemical Properties

• Flash Point: 12°(54°F)
• Appearance: Yellow/powder
• Density: 7.52 g/mL at 25 °C(lit.)
• Refractive Index: 2.66
• Solubility: Soluble in alcohols
• Water Solubility: Insoluble in water.
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: LEAD TITANIUM OXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: LEAD TITANIUM OXIDE(12060-00-3)
• EPA Substance Registry System: LEAD TITANIUM OXIDE(12060-00-3)

Safety Data

• Hazard Codes: Xn,N,T
• Statements: 20-62-50/53-33-20/22-61
• Safety Statements: 22-26-28-36/37/39-45-61-60-53
• RIDADR: 2291
• WGK Germany: 2
• RTECS: XR1575000
• TSCA: Yes
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 12060-00-3(Hazardous Substances Data)

Usage

Uses

Used in Surface Coatings:
Lead Titanate is used as a pigment in outdoor paints due to its yellow color and stability.
Used in Ceramic Insulators:
Lead Titanate is used as a component of ceramic electrical insulators for its insulating properties.
Used in Ceramic Ferroelectric-Piezoelectric Compositions:
Lead Titanate is used as a component in these compositions for its piezoelectric properties, which can convert mechanical stress into electrical energy and vice versa.
Used in Ceramic Electrical Capacitors:
Lead Titanate is used in the production of ceramic electrical capacitors, contributing to their capacitive properties.
Used in Ceramic Glazes:
Lead Titanate is used in ceramic glazes, providing a yellow color and enhancing the glaze's properties.
Used in Transducers:
Lead Titanate is used in transducers for its piezoelectric properties, allowing for the conversion of energy between different forms.
Used in Low Melting Glass Sealants:
Lead Titanate is used in low melting glass sealants for its ability to lower the melting point and improve sealing performance.
Used in Oxidation Catalysts:
Lead Titanate is used as an oxidation catalyst in the manufacturing of acrylonitrile from propylene and nitrous oxide, facilitating the chemical reaction.
Used in Ceramic Capacitor Industry:
Lead Titanate is used as a material in ceramic capacitors, enhancing their performance.
Used in Ceramic Filter Industry:
Lead Titanate is used in ceramic filters for its electrical properties, improving the filter's performance.
Used in PTC Thermal Resistor Industry:
Lead Titanate is used in Positive Temperature Coefficient (PTC) thermal resistors, contributing to their self-regulating temperature properties.
Used in Pressure Sensitive Resistor Industry:
Lead Titanate is used in pressure-sensitive resistors, allowing them to change resistance based on applied pressure.
Used in Transducer Performance Field:
Lead Titanate is used in the performance of transducers, leveraging its piezoelectric properties for energy conversion.

Flammability and Explosibility

Nonflammable

InChI:InChI=1/4O.Pb.Ti/q4*-1;+4;/rO4Ti.Pb/c1-5(2,3)4;/q-4;+4

Upstream product

• 6080-56-4 lead(II) acetate trihydrate 
• 5593-70-4 titanium (IV) butoxide 

Relevant articles and documents

Rietveld analysis of the structure of Pb1-xTix O1+x by neutron diffraction

The Rietveld neutron powder profile analysis of Pb1-xTixO1+x is reported. The structure is similar to the ∝-PbO one (P 4/nmm; Z=2). A contraction of the cell parameters is observed when substituting titanium for lead. The

Preparation of Undoped Lead Titanate Ceramics via Sol-Gel Processing

Crack-free, undoped PbTiO3 ceramics were fabricated successfully using sol-gel-synthesized powder prepared from chelated titanium alkoxide and lead acetate. The sintered ceramics, 8.3 mm in diameter and 6-8 mm thick, were 96% dense. In the present study, PbTiO3 ceramics with excess lead (Pb:Ti = 1.1:1.0) had large grains, averaging 14.3 μm. Lower-lead ceramics (Pb:Ti = 1.0:1.0 and 0.9:1.0) had smaller grains, averaging 1.8 μm. The PbTiO3 ceramics with a high lead content cracked during sintering at 1150°C, whereas the other ceramics did not crack. Excess lead, in a more-than-stoichiometric ratio, promoted grain growth and caused disintegration of the ceramics. Therefore, uncracked PbTiO3 ceramics apparently can be fabricated by avoiding excess lead, possibly because restricted grain growth in low-lead ceramics causes low residual stress over many small grains during transition. The electrical properties measured in the present study for PbTiO3 ceramics with a Pb:Ti ratio of 1:1 are d33 = 35 pC/N, K3 = 64, kp = 0.59, and kt ≈ 0.