HYPERVALENT IODINE OXIDATION OF TRIMETHYLSILYL ENOL ETHERS OF KETONES: A DIRECT SYNTHESIS OF α-KETO TRIFLATES
α-Trifluroromethanesulfonoxy ketones (α-keto triflates) have been synthesized under very mild conditions by the reaction of silyl ethers of ketones and trimethylsilyl trifluoromethanesulfonate/iodosobenzene in dichloromethane.
Moriarty, Robert M.,Epa, W. Ruwan,Penmasta, Raju,Awasthi, Alok K.