NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES
1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr
Saso, Haruo,Ando, Wataru,Ueno, Katsuhiko
p. 1929 - 1940
(2007/10/02)
Palladium Catalyzed Reactions of Neopentylidenesiliranes
Palladium catalyzed reactions of neopentylidenesiliranes with unsaturated compounds have been studied.Two ring expansion products were obtained from the reaction of 1,1-dimesityl-2-Z-neopentylidenesilirane with dimethyl acetylenedicarboxylate, and their r
Saso, Haruo,Ando, Wataru
p. 1567 - 1570
(2007/10/02)
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