122507-63-5Relevant academic research and scientific papers
NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES
Saso, Haruo,Ando, Wataru,Ueno, Katsuhiko
, p. 1929 - 1940 (2007/10/02)
1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr
Palladium Catalyzed Reactions of Neopentylidenesiliranes
Saso, Haruo,Ando, Wataru
, p. 1567 - 1570 (2007/10/02)
Palladium catalyzed reactions of neopentylidenesiliranes with unsaturated compounds have been studied.Two ring expansion products were obtained from the reaction of 1,1-dimesityl-2-Z-neopentylidenesilirane with dimethyl acetylenedicarboxylate, and their r
