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Bis(3,5-dimethyl-4-methoxyphenyl)phosphine, an organophosphorus compound, is widely recognized for its high stability and valuable applications in chemical research and industrial processes. It is commonly used as a ligand in coordination chemistry and catalysis, playing a crucial role in facilitating various reactions by forming strong coordination bonds with metal ions, thus increasing their reactivity and selectivity.

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  • 122708-97-8 Structure
  • Basic information

    1. Product Name: BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE
    2. Synonyms: BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE;Bis(3,5-dimethyl-4-methoxyphenyl)phosphine,97+%
    3. CAS NO:122708-97-8
    4. Molecular Formula: C18H23O2P
    5. Molecular Weight: 302.35
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 122708-97-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE(CAS DataBase Reference)
    10. NIST Chemistry Reference: BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE(122708-97-8)
    11. EPA Substance Registry System: BIS(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINE(122708-97-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 122708-97-8(Hazardous Substances Data)

122708-97-8 Usage

Uses

Used in Chemical Research:
Bis(3,5-dimethyl-4-methoxyphenyl)phosphine is used as a ligand in coordination chemistry for its ability to form strong coordination bonds with metal ions, enhancing the reactivity and selectivity of various reactions.
Used in Industrial Processes:
Bis(3,5-dimethyl-4-methoxyphenyl)phosphine is used as a stabilizing agent for metal complexes in industrial processes, contributing to the efficiency and effectiveness of metal-catalyzed reactions.
Used in Organic Synthesis:
Bis(3,5-dimethyl-4-methoxyphenyl)phosphine is used as a ligand in organic synthesis to facilitate various reactions, improving the overall yield and selectivity of the synthesized compounds.
Used in Catalysis:
Bis(3,5-dimethyl-4-methoxyphenyl)phosphine is used as a ligand in catalysis to enhance the catalytic activity of metal complexes, enabling more efficient and selective transformations in various chemical reactions.

Check Digit Verification of cas no

The CAS Registry Mumber 122708-97-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,7,0 and 8 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 122708-97:
(8*1)+(7*2)+(6*2)+(5*7)+(4*0)+(3*8)+(2*9)+(1*7)=118
118 % 10 = 8
So 122708-97-8 is a valid CAS Registry Number.

122708-97-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name bis(4-methoxy-3,5-dimethylphenyl)phosphane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:122708-97-8 SDS

122708-97-8Relevant articles and documents

Catalyst-free alcoholysis of phosphane-boranes: a smooth, cheap, and efficient deprotection procedure

Van Overschelde, Michel,Vervecken, Elias,Modha, Sachin G.,Cogen, Simon,Van der Eycken, Erik,Van der Eycken, Johan

experimental part, p. 6410 - 6415 (2009/12/09)

Catalyst-free alcoholytic deprotection of borane-protected phosphorus compounds offers a smooth, efficient, and clean alternative to existing deprotection methods. In this paper we report our results on the general applicability of deprotecting phosphane-

Electronic and steric effects of ligands as control elements for rhodium-catalyzed asymmetric hydrogenation

Herseczki, Zsanett,Gergely, Ildiko,Hegedues, Csaba,Szoellosy, Aron,Bakos, Jozsef

, p. 1673 - 1676 (2007/10/03)

Chiral diphosphine ligands analogous to bdpp have been synthesized and tested in order to study the effect of the electronic nature of the ligands in Rh-catalyzed asymmetric hydrogenation of some prochiral olefins. The results are compared with those obtained with the analogous unsubstituted ligand (bdpp). The rhodium-catalyzed asymmetric hydrogenation of olefins was influenced by ligand-based electronic effects, as well as substrate based ones. Excellent ee's (up to 98.3%) have been obtained in the rhodium-catalyzed hydrogenation of (Z)-α-acetamidocinnamic acids and esters.

Rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents to 5,6-dihydro-2(1H)-pyridinones. Asymmetric synthesis of 4-aryl-2-piperidinones

Senda,Ogasawara,Hayashi

, p. 6852 - 6856 (2007/10/03)

Catalytic asymmetric synthesis of 4-aryl-2-piperidinones was realized for the first time by asymmetric 1,4-addition of arylboron reagents to 5,6-dihydro-2(1H)-pyridinones in the presence of a chiral bisphosphine-rhodium catalyst. In the reaction introduci

HIGHLY EFFICIENT ASYMMETRIC HYDROGENATION OF ITACONIC ACID DERIVATIVES CATALYZED BY A MODIFIED DIOP-RHODIUM COMPLEX

Morimoto, Toshiaki,Chiba, Mitsuo,Achiwa, Kazuo

, p. 735 - 738 (2007/10/02)

A modified DIOP analogue bearing 4-methoxy and 3,5-dimethyl groups on each phenyl group has been synthesized.The rhodium complex of the ligand has been found to give very high optical yields in the asymmetric hydrogenation of itaconic acid and its derivatives bearing β-aryl groups, the products of which are key-intermediates for optically active lignan derivatives.

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