EPR SPECTROSCOPY OF A DIAZA DERIVATIVE OF META-XYLYLENE
Photolysis of 2,4,6-trifluoro-1,3-diazidobenzene in 2-methyltetrahydrofuran at 77k produces a dinitrene quintet.Upon warming the quintet briefly to 100K followed by recooling to 77K the EPR spectrum of the quintet disappears and is replaced by that of a trifluorodiaza biradical.
Haider, Karl,Soundararajan, N.,Shaffer, Myron,Platz, Matthew S.
p. 1225 - 1228
(2007/10/02)
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