EPR SPECTROSCOPY OF A DIAZA DERIVATIVE OF META-XYLYLENE
Photolysis of 2,4,6-trifluoro-1,3-diazidobenzene in 2-methyltetrahydrofuran at 77k produces a dinitrene quintet.Upon warming the quintet briefly to 100K followed by recooling to 77K the EPR spectrum of the quintet disappears and is replaced by that of a trifluorodiaza biradical.
Haider, Karl,Soundararajan, N.,Shaffer, Myron,Platz, Matthew S.
p. 1225 - 1228
(2007/10/02)
Recent Studies of Meta-Xylylene and a Diaza Derivative
A new photochemical precursor to meta-xylylene is reported and its mechanism of action is discussed.A diaza derivative of meta-xylylene is also reported.
Haider, K. W.,Migirdicyan, E.,Platz, M. S.,Soundararajan, N.,Despres, A.
p. 85 - 98
(2007/10/02)
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