1239144-91-2

Basic information

• Product Name: C₁₄H₁₄N₂O₂S
• Synonyms: C₁₄H₁₄N₂O₂S
• CAS NO: 1239144-91-2
• Molecular Weight: 274.343
• Mol File: 1239144-91-2.mol

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₄N₂O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₄N₂O₂S(1239144-91-2)
• EPA Substance Registry System: C₁₄H₁₄N₂O₂S(1239144-91-2)

Safety Data

• Hazardous Substances Data: 1239144-91-2(Hazardous Substances Data)

Upstream product

• 98-09-9 benzenesulfonyl chloride 
• 10087-65-7 2-(3,4-dihydro-2H-pyrrol-5-yl)pyrrole 

Downstream Products

• 1239144-74-1 2-(1-benzylpyrrolidin-2-yl)-1-(benzenesulfonyl)pyrrole 

Relevant articles and documents

Conjugate additions, aza-cope, and dissociative rearrangements and unexpected electrocyclic ring closures in the reactions of 2-(2-Pyrrolidinyl)- substituted heteroaromatic systems with acetylenic sulfones

(Figure presented) The reactions of 2-heteroaryl-substituted pyrrolidines with acetylenic sulfones proceeded via two pathways. The first involves conjugate addition of the pyrrolidine to the acetylenic sulfone to afford a zwitterion, followed by dissociation of the C-N bond and recombination of the resulting carbocation and vinyl anion to afford the corresponding azepine derivative. The second comprises a cascade of conjugate addition, aza-Cope rearrangement and anionic 6π electrocyclic ring-closure steps. The stability of the carbocation intermediate formed by C-N cleavage determines the dominant pathway.