126245-60-1

Basic information

• Product Name: ALLYLBENZENE-2,3,4,5,6-D5
• Synonyms: ALLYLBENZENE-2,3,4,5,6-D5
• CAS NO: 126245-60-1
• Molecular Formula: C₉H₁₀
• Molecular Weight: 123.21
• Mol File: 126245-60-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ALLYLBENZENE-2,3,4,5,6-D5(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYLBENZENE-2,3,4,5,6-D5(126245-60-1)
• EPA Substance Registry System: ALLYLBENZENE-2,3,4,5,6-D5(126245-60-1)

Safety Data

• Hazardous Substances Data: 126245-60-1(Hazardous Substances Data)

Upstream product

• 1076-43-3 benzene-d6 
• 762-72-1 allyl-trimethyl-silane 
• 4165-57-5 bromobenzene-d5 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Palladium-Catalyzed meta-C-H Olefination of Arene-Tethered Diols Directed by Well-Designed Pyrimidine-Based Group

The palladium-catalyzed meta-olefination of arene-tethered diols attached to a well-designed pyrimidine moiety is presented. Applications of the protocol are illustrated by the synthesis of various diol-based natural products, such as coumarins, phenylpropanoids, stilbenes, and chalcones. Advantages of this method are demonstrated through the easy removal of the template and a gram-scale olefination reaction. Finally, experimental verification, including 1H NMR, ESI-MS and IR, and DFT studies are undertaken to elucidate the mechanistic complexity.

Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane: Allylation of Aromatic Compounds with Allylmetal and Allylthallium Bis(trifluoroacetate)

A direct allylation of aromatic compounds using allylsilane, allylgermane, or allylstannane (1) and arylthallium bis(trifluoroacetate) has been developed.The actual transmetalation reagent for 1 in the reaction was proposed to be thallium (III) trifluoroacetate (2), which was proposed together with diarylthallium trifluoroacetate by the disproportionation of arylthallium bis(trifluoroacetate).Keywords-allylation of aromatic compound; allylsilane; allylgermane; allylstannane; arylthallium bis(trifluoroacetate)