ALLYLBENZENE-2,3,4,5,6-D5

Base Information

• Chemical Name: ALLYLBENZENE-2,3,4,5,6-D5
• CAS No.: 126245-60-1
• Molecular Formula: C₉H₁₀
• Molecular Weight: 123.139
• Mol file: 126245-60-1.mol

Synonyms:allyl-pentadeuterio-benzene

Chemical Property of ALLYLBENZENE-2,3,4,5,6-D5

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Allylbenzene-2,3,4,5,6-d5 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ALLYLBENZENE-2,3,4,5,6-D5

There total 3 articles about ALLYLBENZENE-2,3,4,5,6-D5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromobenzene-d5 (4165-57-5) + 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (72824-04-5) → allyl-pentadeuterio-benzene (126245-60-1)

Guidance literature:

bromobenzene-d5; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; cesium fluoride; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; at 78 ℃; for 25h; Inert atmosphere;

DOI:10.1021/acs.orglett.9b00433

Reference yield:

benzene-d6 (1076-43-3) + allyl-trimethyl-silane (762-72-1) → allyl-pentadeuterio-benzene (126245-60-1)

Guidance literature:

With phenylthalium(III) di(trifluoroacetate); for 2.5h; Ambient temperature;

Reference yield:

→ allyl-pentadeuterio-benzene (126245-60-1)

Guidance literature:

Perdeuterobrombenzol, 1. Mg, 2. Allylchlorid;

upstream raw materials:

benzene-d6

allyl-trimethyl-silane

bromobenzene-d5

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Refernces

• 1、 Ochiai, Masahito,Fujita, Eiichi,Arimoto, Masao,Yamaguchi, Hideo. "Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane: Allylation of Aromatic Compounds with Allylmetal and Allylthallium Bis(trifluoroacetate)". . p. 3994 - 3999. Retrieved 2007/10/02.