126613-06-7

Basic information

• Product Name: (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
• Synonyms: TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANESULFONYLOXY-[1,1']BINAPHTHALENYL-2-YL ESTER;(R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE);(R)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANE)SULPHONATE;(R)-(-)-1,1'-BINAPHTHOL-2,2'-BIS(TRIFLUOROMETHANESULFONATE);(R)-(-)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE;(R)-1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE);(R)-(-)-1,1'-BI-2-NAPHTHYL BIS-TRIFLUOROMETHANESULFONATE;(R)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
• CAS NO: 126613-06-7
• Molecular Formula: C₂₂H₁₂F₆O₆S₂
• Molecular Weight: 550.45
• Product Categories: API intermediates;Asymmetric Synthesis;Synthetic Organic Chemistry;BINOL Series;Chiral Oxygen
• Mol File: 126613-06-7.mol

Chemical Properties

• Melting Point: 83-85 °C(lit.)
• Boiling Point: 578.8 °C at 760 mmHg
• Flash Point: 303.9 °C
• Appearance: White/Powder
• Density: 1.5402 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility: Insoluble
• Sensitive: moisture sensitive
• BRN: 4282753
• CAS DataBase Reference: (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)(126613-06-7)
• EPA Substance Registry System: (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)(126613-06-7)

Safety Data

• Hazard Codes: C,Xi
• Statements: 34
• Safety Statements: 26-36/37/39-45-27
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• F: 10-21
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 126613-06-7(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) is used as a key intermediate for the synthesis of heterobidentate ligands, which are crucial in asymmetric catalysis. These ligands are essential for enhancing the selectivity and efficiency of various chemical reactions, particularly in the pharmaceutical and fine chemicals industries.
Used in the Preparation of Chiral Ligands:
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) is used as a starting material to prepare 2-(diphenylphosphino)-2'-alkoxy-1,1'-binaphthyls by reacting with bis(aryl) phosphonic acids. These chiral ligands are vital in the development of enantioselective catalysts, which are widely used in the synthesis of chiral compounds with high optical purity.
Used in Catalyst Development:
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) serves as a starting material for the synthesis of binaphthyl-based rhodium catalysts. These catalysts are employed in the hydrogenation of styrene and other related reactions, leading to the production of valuable chemicals and materials with high enantioselectivity and efficiency.

Upstream product

• 335-05-7 Trifluoromethanesulfonyl fluoride 
• 18531-99-2 (S)-[1,1']-binaphthalenyl-2,2'-diol 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 18531-94-7 (R)-1,1'-Bi-2-naphthol 
• 602-09-5 1,1'-bi-2-naphthol 
• 108-48-5 2,6-dimethylpyridine 
• 1025373-45-8 trifluoromethanesulfonic acid anhydride 
• 141807-44-5 (+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl 
• 37595-74-7 N,N-phenylbistrifluoromethane-sulfonimide 

Downstream Products

• 1523504-20-2 C₃₆H₂₂AuF₆IN₂ 
• 1523504-20-2 C₃₆H₂₂AuF₆IN₂ 
• 1523504-41-7 C₄₂H₂₆AuBrF₆N₂ 
• 1523504-41-7 C₄₂H₂₆AuBrF₆N₂ 

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