Welcome to LookChem.com Sign In|Join Free

CAS

  • or

37595-74-7

Post Buying Request

37595-74-7 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • N,N-Bis(trifluoromethylsulfonyl)aniline CAS 37595-74-7 In stock N-Phenyl-bis(trifluoromethanesulfonimide)

    Cas No: 37595-74-7

  • USD $ 1.0-1.0 / Metric Ton

  • 1 Metric Ton

  • 5 Metric Ton/Day

  • Chemwill Asia Co., Ltd.
  • Contact Supplier

37595-74-7 Usage

Chemical Properties

white to off-white crystalline powder

Uses

Different sources of media describe the Uses of 37595-74-7 differently. You can refer to the following data:
1. N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists usefu l in pharmaceutical application.
2. N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.
3. Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubesReactant for: Synthesis of amphoteric alpha-boryl aldehydes Enantioselective synthesis of core ring skeleton of leucosceptroids A-D Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate Stereoselective sulfoxidation

Check Digit Verification of cas no

The CAS Registry Mumber 37595-74-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,5,9 and 5 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 37595-74:
(7*3)+(6*7)+(5*5)+(4*9)+(3*5)+(2*7)+(1*4)=157
157 % 10 = 7
So 37595-74-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H

37595-74-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L12531)  N-Phenylbis(trifluoromethanesulfonimide), 99%   

  • 37595-74-7

  • 1g

  • 118.0CNY

  • Detail
  • Alfa Aesar

  • (L12531)  N-Phenylbis(trifluoromethanesulfonimide), 99%   

  • 37595-74-7

  • 5g

  • 343.0CNY

  • Detail
  • Alfa Aesar

  • (L12531)  N-Phenylbis(trifluoromethanesulfonimide), 99%   

  • 37595-74-7

  • 25g

  • 1684.0CNY

  • Detail
  • Aldrich

  • (295973)  N-Phenyl-bis(trifluoromethanesulfonimide)  99%

  • 37595-74-7

  • 295973-5G

  • 427.05CNY

  • Detail
  • Aldrich

  • (295973)  N-Phenyl-bis(trifluoromethanesulfonimide)  99%

  • 37595-74-7

  • 295973-25G

  • 1,786.59CNY

  • Detail
  • Aldrich

  • (78175)  N-Phenyl-bis(trifluoromethanesulfonimide)  ≥98.0% (HPLC)

  • 37595-74-7

  • 78175-5G

  • 866.97CNY

  • Detail
  • Aldrich

  • (78175)  N-Phenyl-bis(trifluoromethanesulfonimide)  ≥98.0% (HPLC)

  • 37595-74-7

  • 78175-25G

  • 3,334.50CNY

  • Detail
  • Aldrich

  • (78175)  N-Phenyl-bis(trifluoromethanesulfonimide)  ≥98.0% (HPLC)

  • 37595-74-7

  • 78175-50G

  • 5,806.71CNY

  • Detail

37595-74-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N-Bis(trifluoromethylsulfonyl)aniline

1.2 Other means of identification

Product number -
Other names N-Phenyltrifluoromethanesulfonimide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:37595-74-7 SDS

37595-74-7Synthetic route

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

aniline
62-53-3

aniline

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
Stage #1: trifluoromethylsulfonic anhydride; aniline With 1,4-diaza-bicyclo[2.2.2]octane In acetonitrile at 40℃; under 600.06 - 1725.17 Torr; for 8h; Sealed tube; Large scale;
Stage #2: With dmap In dichloromethane; acetonitrile under 450.045 - 1575.16 Torr; for 15h; Sealed tube; Large scale;
94%
With triethylamine In dichloromethane at 25℃; for 16h; Inert atmosphere; Industry scale; Cooling with ice;86%
With triethylamine In dichloromethane at 20℃; Cooling with ice;86%
C10F17IN2O8S4

C10F17IN2O8S4

bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

benzene
71-43-2

benzene

A

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

B

C14H5F11INO4S2

C14H5F11INO4S2

Conditions
ConditionsYield
at 120℃; Glovebox;A 7%Spectr.
B 93%
Trifluoromethanesulfonyl fluoride
335-05-7

Trifluoromethanesulfonyl fluoride

aniline
62-53-3

aniline

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
Stage #1: Trifluoromethanesulfonyl fluoride; aniline With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 60℃; under 675.068 Torr; for 8h; Sealed tube; Large scale;
Stage #2: With dmap In toluene at 60℃; under 750.075 - 1950.2 Torr; for 10h; Pressure; Solvent; Sealed tube; Large scale;
92.1%
With dmap; potassium carbonate In dichloromethane at -40 - 0℃; under 150.015 - 750.075 Torr; for 12h; Reagent/catalyst;90.7%
Li(1+)*C6H5N(SO2CF3)(1-)=C6H5NLi(SO2CF3)

Li(1+)*C6H5N(SO2CF3)(1-)=C6H5NLi(SO2CF3)

trifluoromethane sulfonyl chloride
421-83-0

trifluoromethane sulfonyl chloride

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
In tetrahydrofuran60%
In tetrahydrofuran60%
Na(1+)*CF3SO2NC6H5(1-)=NaCF3SO2NC6H5

Na(1+)*CF3SO2NC6H5(1-)=NaCF3SO2NC6H5

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
In freon 113=1,1,2-trichloro-trifluoroethane at 95°C;34%
In 1,1,2-Trichloro-1,2,2-trifluoroethane
benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

1-butyl-3-methylimidazolium trifluoromethanesulfonimide
174899-83-3

1-butyl-3-methylimidazolium trifluoromethanesulfonimide

A

C8H5F6NO4S2

C8H5F6NO4S2

B

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
With [Bmim][Br] at 24.84℃; for 24h; Kinetics;
at 24.84℃; for 24h; Kinetics;
benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

1-butyl-3-methylimidazolium trifluoromethanesulfonimide
174899-83-3

1-butyl-3-methylimidazolium trifluoromethanesulfonimide

A

C8H5F6NO4S2

C8H5F6NO4S2

B

fluorobenzene
462-06-6

fluorobenzene

C

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
at 90℃; for 0.216667h;
trifluoromethanesulfonic acid anhydride
1025373-45-8

trifluoromethanesulfonic acid anhydride

aniline
62-53-3

aniline

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
With triethylamine In dichloromethane at -78 - 20℃; Inert atmosphere;
trifluoromethane sulfonyl chloride
421-83-0

trifluoromethane sulfonyl chloride

aniline
62-53-3

aniline

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 2h;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

methyl 2,2-dimethyl-3-oxobutanoate
38923-57-8

methyl 2,2-dimethyl-3-oxobutanoate

methyl 2,2-dimethyl-3-0-(trifluoromethanesulfonate)-but-3-enoate
143225-17-6

methyl 2,2-dimethyl-3-0-(trifluoromethanesulfonate)-but-3-enoate

Conditions
ConditionsYield
Stage #1: methyl 2,2-dimethyl-3-oxobutanoate With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran; hexane at -78℃; for 1.25h; Inert atmosphere;
100%
Stage #1: methyl 2,2-dimethyl-3-oxobutanoate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -20℃; for 0.166667h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide at -10℃; for 2h;
87%
With lithium diisopropyl amide In tetrahydrofuran -78 deg C to RT;
Stage #1: methyl 2,2-dimethyl-3-oxobutanoate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.258333h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran; hexane Inert atmosphere;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

(1RS,2RS,6SR,7RS,8SR)-7-bromo-3-oxo-1-vinyl-9-azatricyclo[4.4.0.02,8]decane-9-carboxylic acid methyl ester
120566-50-9

(1RS,2RS,6SR,7RS,8SR)-7-bromo-3-oxo-1-vinyl-9-azatricyclo[4.4.0.02,8]decane-9-carboxylic acid methyl ester

(1RS,2RS,6SR,7RS,8SR)-7-bromo-3-trifluoromethanesulfonyloxy-1-vinyl-9-azatricyclo[4.4.0.02,8]dec-3-ene-9-carboxylic acid methyl ester
120566-52-1

(1RS,2RS,6SR,7RS,8SR)-7-bromo-3-trifluoromethanesulfonyloxy-1-vinyl-9-azatricyclo[4.4.0.02,8]dec-3-ene-9-carboxylic acid methyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78 - 0℃;100%
Stage #1: (1RS,2RS,6SR,7RS,8SR)-7-bromo-3-oxo-1-vinyl-9-azatricyclo[4.4.0.02,8]decane-9-carboxylic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran; hexane at -78 - 0℃;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

6-methoxy-3,4-dihydro-1(2H)-naphthalenone
1078-19-9

6-methoxy-3,4-dihydro-1(2H)-naphthalenone

6-methoxy-3,4-dihydronaphthalene-1-yl triflate
115375-59-2

6-methoxy-3,4-dihydronaphthalene-1-yl triflate

Conditions
ConditionsYield
Stage #1: 6-methoxy-3,4-dihydro-1(2H)-naphthalenone With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 0.75h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 0℃; for 3h;
100%
With lithium hexamethyldisilazane In tetrahydrofuran at -78 - 20℃; for 16h; Inert atmosphere;89%
Stage #1: 6-methoxy-3,4-dihydro-1(2H)-naphthalenone With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
80%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

3-hydroxy-benzeneacetic acid, methyl ester
42058-59-3

3-hydroxy-benzeneacetic acid, methyl ester

methyl [3-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-acetate
147283-87-2

methyl [3-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-acetate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane Ambient temperature;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2,2-dimethyl-cyclohexanone
1193-47-1

2,2-dimethyl-cyclohexanone

6,6-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate
32363-23-8

6,6-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate

Conditions
ConditionsYield
Stage #1: 2,2-dimethyl-cyclohexanone With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78℃;
100%
Stage #1: 2,2-dimethyl-cyclohexanone With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 23℃;
100%
Stage #1: 2,2-dimethyl-cyclohexanone With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; for 2.5h; Inert atmosphere;
55%
With lithium diisopropyl amide 1.) THF, -78 deg C, 2 h, 2.) THF, 0 deg C, 12 h; Yield given. Multistep reaction;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

raloxifene
188823-98-5

raloxifene

Trifluoro-methanesulfonic acid 6-[4-(2-piperidin-1-yl-ethoxy)-phenyl]-3-trifluoromethanesulfonyloxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yl ester
188824-03-5

Trifluoro-methanesulfonic acid 6-[4-(2-piperidin-1-yl-ethoxy)-phenyl]-3-trifluoromethanesulfonyloxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yl ester

Conditions
ConditionsYield
With triethylamine; N,N-dimethyl-formamide In tetrahydrofuran for 12h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

(4aS,5R,6R,8aS)-5,6,8a-Trimethyl-5-(2-triisopropylsilanyloxy-ethyl)-octahydro-naphthalen-1-one
214413-28-2

(4aS,5R,6R,8aS)-5,6,8a-Trimethyl-5-(2-triisopropylsilanyloxy-ethyl)-octahydro-naphthalen-1-one

Trifluoro-methanesulfonic acid (4aS,5R,6R,8aS)-5,6,8a-trimethyl-5-(2-triisopropylsilanyloxy-ethyl)-3,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl ester
218453-51-1

Trifluoro-methanesulfonic acid (4aS,5R,6R,8aS)-5,6,8a-trimethyl-5-(2-triisopropylsilanyloxy-ethyl)-3,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl ester

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h; Esterification;100%
With lithium diisopropyl amide Yield given. Multistep reaction;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

dimethyl 2-hydroxy-5-iodoisophthalate

dimethyl 2-hydroxy-5-iodoisophthalate

dimethyl 5-iodo-2-{[(trifluoromethyl)sulphonyl]oxy}isophthalate
263160-77-6

dimethyl 5-iodo-2-{[(trifluoromethyl)sulphonyl]oxy}isophthalate

Conditions
ConditionsYield
With triethylamine In acetonitrile at 20℃; for 16h; sulphonylation;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2,6-dimethyl-4-nitro phenol
2423-71-4

2,6-dimethyl-4-nitro phenol

2,6-dimethyl-4-nitrophenyl trifluoromethanesulphonate
156740-78-2

2,6-dimethyl-4-nitrophenyl trifluoromethanesulphonate

Conditions
ConditionsYield
With sodium hydride In DMF (N,N-dimethyl-formamide) at 0℃; for 2h;100%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 8h; Acylation;89%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

5-dodecanolide
713-95-1

5-dodecanolide

trifluoro-methanesulfonic acid 6-heptyl-5,6-dihydro-4H-pyran-2-yl ester
445462-86-2

trifluoro-methanesulfonic acid 6-heptyl-5,6-dihydro-4H-pyran-2-yl ester

Conditions
ConditionsYield
With potassium hexamethylsilazane In tetrahydrofuran; toluene at -78℃; for 0.25h;100%
With potassium hexamethylsilazane In tetrahydrofuran; toluene at -78℃; for 0.25h;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

4-(benzo[d]oxazol-2ʹ-yl)-2-methoxyphenol
3164-07-6

4-(benzo[d]oxazol-2ʹ-yl)-2-methoxyphenol

4-(1,3-benzoxazol-2-yl)-2-methoxyphenyl trifluoromethanesulfonate
540497-27-6

4-(1,3-benzoxazol-2-yl)-2-methoxyphenyl trifluoromethanesulfonate

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 0.5h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

1-(3-methoxy-4-hydroxyphenyl)ethanone
498-02-2

1-(3-methoxy-4-hydroxyphenyl)ethanone

4-acetyl-2-methoxyphenyl trifluoromethanesulfonate
149105-13-5

4-acetyl-2-methoxyphenyl trifluoromethanesulfonate

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide; acetonitrile at 20℃; for 12h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

7-Methoxy-1-tetralone
6836-19-7

7-Methoxy-1-tetralone

trifluoromethanesulfonic acid 7-methoxy-3,4-dihydronaphthalen-1-yl ester
724707-85-1

trifluoromethanesulfonic acid 7-methoxy-3,4-dihydronaphthalen-1-yl ester

Conditions
ConditionsYield
Stage #1: 7-Methoxy-1-tetralone With lithium hexamethyldisilazane In tetrahydrofuran at -79℃; for 0.75h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 0℃; for 3h;
100%
With potassium hexamethylsilazane In tetrahydrofuran at -78℃; for 1h;96%
With potassium hexamethylsilazane In tetrahydrofuran at -78℃; for 1.5h;96%
cyclohexanedione monoethylene ketal
4746-97-8

cyclohexanedione monoethylene ketal

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

1,4-dioxaspiro[4.5]dec-7-en-8-yl trifluoromethanesulfonate
170011-47-9

1,4-dioxaspiro[4.5]dec-7-en-8-yl trifluoromethanesulfonate

Conditions
ConditionsYield
With potassium hexamethylsilazane In tetrahydrofuran; toluene at -78℃; for 4h;100%
With lithium hexamethyldisilazane In tetrahydrofuran at -78 - 20℃; for 0.5h; Inert atmosphere;100%
With lithium hexamethyldisilazane at -78 - 20℃; Inert atmosphere;100%
Norbornan-2-on
497-38-1

Norbornan-2-on

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2-trifluoromethanesulfonyloxybicyclo[2.2.1]hept-2-ene
82361-91-9

2-trifluoromethanesulfonyloxybicyclo[2.2.1]hept-2-ene

Conditions
ConditionsYield
Stage #1: Norbornan-2-on With lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; for 3h; Inert atmosphere;
100%
With n-butyllithium; diisopropylamine In tetrahydrofuran59%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

5-(4-hydroxy-phenyl)-pyrrolidin-2-one
207989-87-5

5-(4-hydroxy-phenyl)-pyrrolidin-2-one

γ-4-trifluoromethylsulphonyloxyphenyl-γ-butyrolactam
207989-88-6

γ-4-trifluoromethylsulphonyloxyphenyl-γ-butyrolactam

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;100%
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;96%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

3-[6-amino-8-(3-bromophenyl)-2,3,4,8-tetrahydroimidazo[1,5-a]pyrimidin-8-yl]phenol

3-[6-amino-8-(3-bromophenyl)-2,3,4,8-tetrahydroimidazo[1,5-a]pyrimidin-8-yl]phenol

3-[6-amino-8-(3-bromophenyl)-2,3,4,8-tetrahydroimidazo[1,5-a]pyrimidin-8-yl]phenyl trifluoromethanesulfonate

3-[6-amino-8-(3-bromophenyl)-2,3,4,8-tetrahydroimidazo[1,5-a]pyrimidin-8-yl]phenyl trifluoromethanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 25℃; for 12h;100%
With triethylamine In dichlorometane at 0 - 25℃; for 12h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

1-[7-(5-cyanopyridin-2-yl)-5-hydroxybenzothiazol-2-yl]-3-ethylurea
1000289-72-4

1-[7-(5-cyanopyridin-2-yl)-5-hydroxybenzothiazol-2-yl]-3-ethylurea

trifluoromethanesulfonic acid 7-(5-cyanopyridin-2-yl)-2-(3-ethylureido)benzothiazol-5-yl ester
1000289-73-5

trifluoromethanesulfonic acid 7-(5-cyanopyridin-2-yl)-2-(3-ethylureido)benzothiazol-5-yl ester

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 20℃; for 2h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

3-hydroxy-6-methyl-2-(O-tert-butyldimethylsilyl)hydroxymethylpyran-4(1H)-one
958457-26-6

3-hydroxy-6-methyl-2-(O-tert-butyldimethylsilyl)hydroxymethylpyran-4(1H)-one

6-methyl-2-(O-tert-butyldimethylsilyl)hydroxymethyl-3-trifluoromethanesulfonyloxy-pyran-4(1H)-one
958457-27-7

6-methyl-2-(O-tert-butyldimethylsilyl)hydroxymethyl-3-trifluoromethanesulfonyloxy-pyran-4(1H)-one

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 1.5h; Inert atmosphere;100%
With potassium carbonate In N,N-dimethyl-formamide at 20℃;
With potassium carbonate In N,N-dimethyl-formamide for 1.66667h;
C27H32O10SSiN2

C27H32O10SSiN2

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

C28H31F3O12S2SiN2

C28H31F3O12S2SiN2

Conditions
ConditionsYield
With 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine In tetrahydrofuran at 20℃;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2-fluoro-5-(8-fluoro-7-trifluoromethylquinolin-4-yl)phenol
693818-37-0

2-fluoro-5-(8-fluoro-7-trifluoromethylquinolin-4-yl)phenol

trifluoromethanesulphonic acid 2-fluoro-5-(8-fluoro-7-trifluoromethyl-quinolin-4-yl)phenyl ester
693818-38-1

trifluoromethanesulphonic acid 2-fluoro-5-(8-fluoro-7-trifluoromethyl-quinolin-4-yl)phenyl ester

Conditions
ConditionsYield
With triethylamine at 20℃; for 16h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

methyl 1-hydroxy-5,6,7,8-tetrahydronaphthalene-2-carboxylate
54815-88-2

methyl 1-hydroxy-5,6,7,8-tetrahydronaphthalene-2-carboxylate

methyl 1-{[(trifluoromethyl)sulphonyl]oxy}-5,6,7,8-tetrahydronaphthalene-2-carboxylate
812690-21-4

methyl 1-{[(trifluoromethyl)sulphonyl]oxy}-5,6,7,8-tetrahydronaphthalene-2-carboxylate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; dmap In dichloromethane at 20℃; for 18.5h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

C29H40N2O4
762300-05-0

C29H40N2O4

C30H39F3N2O6S
762300-07-2

C30H39F3N2O6S

Conditions
ConditionsYield
Stage #1: N,N-phenylbistrifluoromethane-sulfonimide; C29H40N2O4 With triethylamine In dichloromethane at 20℃;
Stage #2: With sodium hydroxide In dichloromethane; water at 20℃; for 0.5h;
100%
2-methoxy-8-hydroxyquinoline
74668-72-7

2-methoxy-8-hydroxyquinoline

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

1,1,1-trifluoromethanesulfonic acid 2-methoxyquinolin-8-yl ester
642477-88-1

1,1,1-trifluoromethanesulfonic acid 2-methoxyquinolin-8-yl ester

Conditions
ConditionsYield
With triethylamine In DMF (N,N-dimethyl-formamide) at 40℃; for 8h;100%
C24H31NO

C24H31NO

N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

C25H30F3NO3S

C25H30F3NO3S

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

tert-butyl 5-(methoxymethoxy)-4-(trifluoromethylsulfonyloxy)spiro[chromene-2,4'-piperidine]-1'-carboxylate
911227-82-2

tert-butyl 5-(methoxymethoxy)-4-(trifluoromethylsulfonyloxy)spiro[chromene-2,4'-piperidine]-1'-carboxylate

Conditions
ConditionsYield
Stage #1: tert-butyl 5-(methoxymethoxy)-4-oxospiro[chroman-2,4'-piperidine]-1'-carboxylate With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; for 12h;
100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

C23H22F3NO5S
911228-44-9

C23H22F3NO5S

Conditions
ConditionsYield
Stage #1: benzyl 4-oxo-3,4-dihydro-1H-spiro[naphthalene-2,4'-piperidine]-1'-carboxylate With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 0.75h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at -78 - 20℃; for 2.5h;
100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

(3R,4S)-3-[(3S)-3-{[tert-butyl(dimethyl)silyl]oxy}-3-(4-fluorophenyl)propyl]-4-(3'-hydroxybiphenyl-4-yl)-1-phenylazetidin-2-one
852204-40-1

(3R,4S)-3-[(3S)-3-{[tert-butyl(dimethyl)silyl]oxy}-3-(4-fluorophenyl)propyl]-4-(3'-hydroxybiphenyl-4-yl)-1-phenylazetidin-2-one

4'-{(2S,3R)-3-[(3S)-3-{[tert-butyl(dimethyl)silyl]oxy}-3-(4-fluorophenyl)propyl]-4-oxo-1-phenylazetidin-2-yl}biphenyl-3-yl trifluoromethanesulfonate
852204-41-2

4'-{(2S,3R)-3-[(3S)-3-{[tert-butyl(dimethyl)silyl]oxy}-3-(4-fluorophenyl)propyl]-4-oxo-1-phenylazetidin-2-yl}biphenyl-3-yl trifluoromethanesulfonate

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 20℃; for 2h;100%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinol
920511-31-5

2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinol

2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl trifluoromethanesulfonate
920511-33-7

2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl trifluoromethanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane100%
With triethylamine In dichloromethane at 20℃;
With triethylamine In dichloromethane at 20℃;
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

tert-butyl [6-hydroxy-2-isobutyl-4-(4-methylphenyl)-1-oxo-1,2-dihydro-3-isoquinolinyl]methylcarbamate

tert-butyl [6-hydroxy-2-isobutyl-4-(4-methylphenyl)-1-oxo-1,2-dihydro-3-isoquinolinyl]methylcarbamate

tert-butyl [2-isobutyl-4-(4-methylphenyl)-1-oxo-6-trifluoromethanesulfonyloxy-1,2-dihydro-3-isoquinolinyl]methylcarbamate

tert-butyl [2-isobutyl-4-(4-methylphenyl)-1-oxo-6-trifluoromethanesulfonyloxy-1,2-dihydro-3-isoquinolinyl]methylcarbamate

Conditions
ConditionsYield
In N,N-dimethyl-formamide100%

37595-74-7Relevant articles and documents

Preparation method of N-phenyl bis (trifluoromethanesulfonyl) imine

-

Paragraph 0026-0052, (2022/01/12)

The invention relates to a preparation method of N-phenyl bis (trifluoromethanesulfonyl) imine, and belongs to the technical field of chemical engineering. The method comprises the following steps: dissolving trifluoromethanesulfonic acid and organic alkali in an organic solvent, and adding HATU for reaction; the reaction temperature is greater than or equal to 15 DEG C, and the organic solvent is not boiled; after the reaction is finished, a reaction solution containing trifluoromethanesulfonic acid active ester is obtained; adding aniline into the reaction liquid, and reacting at 25 +/-5 DEG C for 6-12 hours; and after the reaction is finished, removing the organic solvent to obtain a crude product containing the N-phenyl bis (trifluoromethanesulfonyl) imine, washing, and recrystallizing and purifying by using an alcohol solvent with 1-3 carbon atoms to obtain the N-phenyl bis (trifluoromethanesulfonyl) imine. The N-phenyl bis (trifluoromethanesulfonyl) imine with high purity and high yield can be prepared by the method, the reaction condition is mild, the utilization rate of raw materials is high, and the method is green and environment-friendly.

Meta Selective C-H Borylation of Sterically Biased and Unbiased Substrates Directed by Electrostatic Interaction

Chaturvedi, Jagriti,Haldar, Chabush,Bisht, Ranjana,Pandey, Gajanan,Chattopadhyay, Buddhadeb

supporting information, p. 7604 - 7611 (2021/05/26)

An electrostatically directed meta borylation of sterically biased and unbiased substrates is described. The borylation follows an electrostatic interaction between the partially positive and negative charges between the ligand and substrate. With this strategy, it has been demonstrated that a wide number of challenging substrates, especially 4-substituted substrates, can selectively be borylated at the meta position. Moreover, unsubstituted substrates also displayed excellent meta selectivity. The reaction employs a bench-stable ligand and proceeds at a milder temperature, precluding the need to synthesize a bulky and sophisticated ligand/template.

Method for preparing N-phenyl-bis (perfluoroalkyl sulfonyl) imide

-

Paragraph 0025-0030, (2020/01/12)

The invention relates to a method for preparing N-phenyl-bis (perfluoroalkyl sulfonyl) imide, and belongs to the technical field of preparation of perfluoroalkyl sulfonylation reagents. According to the method, perfluoroalkyl sulfonyl fluoride and aniline are used as raw materials, and N-phenyl-bis (perfluoroalkyl sulfonyl) imide is prepared under the action of a catalyst. The method disclosed bythe invention is simple in process flow, mild in reaction, good in safety, low in cost, high in yield and high in purity.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 37595-74-7