4-ETHOXYMETHYLENE-2-PHENYL-5(4H)-OXAZOLONE AS A SYNTHON FOR THE SYNTHESIS OF SOME 2H-PYRAN-2-ONES
Treatment of 4-ethoxymethylene-2-phenyl-5(4H)-oxazolone with activated methylene compounds under acidic or basic conditions leads to 2H-pyran-2-ones and fused pyran-2-ones.On the other hand, methyl (3-benzoylamino-5-methoxycarbonyl-2-oxo-2H-pyran-6-yl)acetate (4) has also been prepared by a one-pot synthesis from dimethyl 1,3-acetone dicarboxylate, diethoxymethyl acetate, hippuric acid and acetic anhydride.
Kepe, Vladimir,Kocevar, Marijan,Petric, Andrej,Polanc, Slovenko,Vercek, Bojan
p. 843 - 849
(2007/10/02)
A simple and general one-pot synthesis of some 2h-pyran-2-ones and fused pyran-2-ones
A general one-pot synthesis of some 2H-pyran-2-ones and fused pyran-2-ones starting from 1,3-dlcarbonyl compounds, N-acylglycines and one-carbon synthons (trialkyl orthoformates, diethoxymethyl acetate or N,N-dlmethylformamide dimethyl acetal) in acetic anhydride (or in a mixture of acetic anhydride and acetic acid) is described.
Methyl 2-Benzoylamino-3-dimethylaminopropenoate in the Synthesis of Heterocyclic Systems. The Synthesis of Benzoylamino Substituted 7H-Pyranopyrimidine, 1H,6H-pyrano-pyrazole and 2H-1-benzopyran Derivatives
Methyl 2-benzoylamino-3-dimethylaminopropenoate (6) reacts with heterocyclic compounds containing an active methylene group or potential methylene group in the ring system, such as barbituric acid derivatives 1 and 2, pyrazolones 3 and 4, and resorcinol,
Stanovnik, Branko,Svete, Jurij,Tisler, Miha
p. 1273 - 1276
(2007/10/02)
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